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云师大化工学院叶龙武教授团队在Inorganic Chemistry Frontiers上发表最新成果

已有 647 次阅读 2024-2-21 22:57 |个人分类:云师大研究|系统分类:论文交流

2024年2月6日,Royal Society of Chemistry 旗下知名期刊《Inorganic Chemistry Frontiers》在线发表了云南师范大学化学化工学院高层次柔性引进人才、厦门大学化学化工学院教授叶龙武教授团队的最新研究成果《Orange to red iridium(iii) complexes possessing good electron mobility with a pyrimidine-4-carboxylic acid ligand for high-performance solution-processed OLEDs with an EQE ov》.云南师范大学化学化工学院高层次人才史重阳博士为和滕明瑜 、五邑大学陈钊博士、深圳信息职业技术学院 Guangzhao Lu博士为共同通讯作者。

Abstract

Three novel iridium(III) complexes with pyrimidine carboxylic acid as the auxiliary ligand were designed, showing adjustable emission peak wavelengths from 559 nm to 610 nm with relatively high photoluminescence quantum yields (PLQYs) of 58–89% in CH2Cl2. The structures of the title complexes were confirmed by single-crystal X-ray diffraction (XRD), nuclear magnetic resonance spectroscopy (NMR), and high-resolution mass spectrometry (HRMS). Their electronic states were investigated using time-dependent density functional theory (TD-DFT) calculations. When employing these emitters to fabricate solution-processed organic light-emitting diodes (OLEDs), the obtained orange and red OLEDs exhibit prominent performances with the maximum current efficiencies of 95.4 cd A−1 and 39.8 cd A−1, and the maximum external quantum efficiencies (EQEmax) of 31.3% and 24.7%, both of which are ranked among the highest values for orange and red solution-processed OLEDs.

Graphical abstract: Orange to red iridium(iii) complexes possessing good electron mobility with a pyrimidine-4-carboxylic acid ligand for high-performance solution-processed OLEDs with an EQE over 31%

扩展阅读:

云师大化工学院叶龙武教授团队在Cell Reports Physical Science上发表最新成果

云师大高端引进人才叶龙武团队在《有机化学快报》发表文章

滕明瑜                             

制药工程专业,教授,博士(硕士生)导师

联系方式:myteng@ynnu.edu.cn 

 

主要研究方向

有机光功能材料有机合成;药物合成

 

主要招生专业

无机化学有机化学;制药工程

 

教育与工作经历:

19999月~20036月,浙江大学理学院化学系 化学专业学士

20039月~20066月,浙江工业大学化学工程与材料学院 农药学专业硕士

20069月~200911月,南京大学化学与化学工程学院 化学专业博士

200912月~201211月,南京大学环境科学与工程学院 博士后研究员

20133月~至今云南师范大学化学与化学工程学院 讲师,副教授

20193月~20202月,伦敦大学玛丽女王学院访问学者

 

获奖成果和荣誉称号:

    1. 滕明瑜云南省“兴滇英才支持计划”——青年拔尖人才专项,2020

 

    2. 指导教师:晏瑾,滕明瑜,“国药工程-东富龙杯”全国大学生制药工程设计竞赛二等奖,2022

    3. 李晓梅滕明瑜龚英王琴戎梅竹晏瑾陈云建教学成果奖云南师范大学 二等奖2020

    4. 指导教师:王琴,滕明瑜,“国药工程-东富龙杯”全国大学生制药工程设计竞赛二等奖,2019

    5. 指导教师:滕明瑜,王琴,“国药工程-东富龙杯”全国大学生制药工程设计竞赛二等奖并进入一等奖决赛,2018

 

    6. 指导教师:滕明瑜,戎梅竹,“国药工程-东富龙杯”全国大学生制药工程设计竞赛二等奖,2017

 

    7. 张杰,滕明瑜,李丹台州市自然科学奖等奖,2016

 

     8. 滕明瑜,云南省引进高层次人才工作经费资助,三等奖,2013

 

主持科研项目

           1.  国家自然科学基金地区基金项目,新型Ir()配合物磷光材料的设计、合成及其光电性能研究执行时间:2015/01-2018/12

         2. 云南省基础研究计划项目(面上项目), 新型卤代Ir(III)配合物磷光材料的设计、合成及其光电性能研究),执行时间:2021/04-2024/03

     3. 云南省万人计划“青年拔尖人才”专项,新型Ir(III)配合物磷光材料的设计、合成及其光电性能研究,执行时间:2021/01-2025/12

         4. 云南省基础研究计划项目(面上项目),长寿命芴类PLED材料的合成及性能研究,执行时间:2016/10-2019/09

     5. 横向项目,合成生物学项目合作研发,执行时间:2022/11-2023/11

 

代表性论文、专利等

论文:

1. Chong-Yang Shi, Bo Zhou, Ming-Yu Teng,* Long-Wu Ye.* Recent Advances in Asymmetric [1,2]-Stevens-Type Rearrangement via Metal Carbenes. Synthesis 2023, 55, in press.

2. Chong-Yang Shi, Tao Han, Feng-Lin Hong, Long-Wu Ye,* Qing Sun,* Ming-Yu Teng.* Construction of Spirolactams by Unexpected Oxidative Cyclization of Alkenyl Diynes via Copper Catalysis. Org. Lett. 2023, 25, 1525.

3. Ai-hui Zhou, Tao Han, Peng-bin Si, Xiao-qing Liu, Ming-yu Teng*, Guo-li Huang, Bo Liu, Qin Wang*, Jie Zhang*Synthesis and properties of a series of iridium complexes with naphthalenyl imidazo[2,1-b]thiazole derivatives as primary ligands, JOrganomet. Chem. 2023, 985122596.

4. Ming-yu Teng*, Tao Han, En-he Huang, Long-Wu Ye.*Research Progress on Enantioselective Desymmetrization Reactions Involving Metal Carbenes, Chin. J. Org. Chem. 2022, 423295.

5. Peng-bin Si, Hai-feng Zhe, Ai-hui Zhou, Xiao-qing Liu, Ming-yu Teng*, Mei-zhu Rong, Yu-fei Wang, Qin Wang*, Zheng-liang Wang, Jie Zhang*, Synthesis and photoelectric properties of IrIII complexes using fluorobenzylimidazole[2,1-b]thiazole derivatives as primary ligands, New J. Chem. 2021, 45, 18796.

6. Jie Zhang*, Aiguo Zhong, Guobo Huang, Meiding Yang, Dan Li, Mingyu Teng*, Deman Han, Enhanced efficiency with CDCA co-adsorption for dye-sensitized solar cells based on metallosalophen complexes, Solar Energy 2020, 209, 316.

7. Xin-yin Yin, Zhi-yu Yang, Guo-li Huang, Jian-jian Bian, Deng-qiang Wang, Qin Wang, , Ming-yu Teng*, Zheng-liang Wang*, Jie Zhang*, Synthesis and properties of a series of iridium complexes with imidazolo[2,1-b]thiazole derivatives as primary ligands, New J. Chem. 2019, 43, 5849.

8. Jie Zhang*, Lei Wang, Aiguo Zhong, Guobo Huang, Fengshou Wu*, Dan Li, Mingyu Teng*, Jiali Wang, Deman Han*, Deep red PhOLED from dimeric salophen Platinum(II) complexes, Dyes Pigm. 2019, 162, 590.

Xiao-mei Li, Jie Zhang, Yu-fei Wang, Mei-zhu Rong, Ming-yu Teng*, Jian Liu*, A bipolar thiophene substituted 1,3,5-triazine host material for green phosphorescent OLED with low onset voltage and current efficiency roll-off, Dyes Pigm. 2017, 141, 1.

10. Ming-yu Teng, Jie Zhang, Guo-li Huang, Bo Liu, Xiao-mei Li, Mei-zhu Rong, Tian-hua Shen, Qing-bao Song*, Synthesis and nonlinear optical properties of novel chalcone analogues of ferrocenyl biaryl derivatives, J. Organomet. Chem. 2015, 791, 298.

11. Ming-yu TengSong Zhang, Yi-ming JinTian-yi Li, Xuan Liu, Qiu-lei Xu, Chen Lin, You-xuan Zheng, Leyong Wang, Jing-lin Zuo, Efficient organic light-emitting diodes with low efficiency roll-off at high brightness using iridium emitters based on 2-(4-trifluoromethyl-6-fluoro phenyl)pyridine and tetraphenylimidodiphosphinate derivatives, Dyes Pigm. 2014, 105, 105.

12. Ming-yu Teng*Ying LiuShao-lu LiGuo-li Huang, Juli Jiang*, Leyong Wang, Synthesis, chemo-selective properties of substituted 9-aryl-9H-fluorenes from triarylcarbinols and enantiomerical kinetics of chiral 9-methoxy-11-(naphthalen-1-yl)-11H-benzo[a]fluorene, RSC Adv. 2013, 3, 9016.

13. Ming-yu TengQiu-lei XuHong-yan LiLin Wu, You-xuan Zheng*, Chen Lin*, Leyong Wang, Color changeable OLEDs controlled by doping ratio and driving voltage with an anthracene derivative doped layer, RSC Adv. 2012, 2, 10175.

14. Ming-yu TengSong ZhangSheng-wei JiangXu Yang, Chen Lin, You-xuan Zheng*, Leyong Wang*, Di Wu*, Jing-Lin Zuo, Xiao-zeng You, Electron mobility determination of efficient phosphorescent iridium complexes with tetraphenylimidodiphosphinate ligand via transient electroluminescence method, Appl. Phys. Lett. 2012, 100, 073303.

 

 

专利:

1. 滕明瑜,李晓梅,郭庆美,林睿,梁勇,专利名称:一种2-(苯磺酰基)苯乙酮衍生物为辅助配体的铱配合物,发明专利,专利授权号:ZL201711230061.7,专利授权日期:2022/05

2. 滕明瑜徐秋蕾郑佑轩左景林游效曾,专利名称:一类绿光铱(III)配合物及其制法和在有机电致发光中的应用,发明专利,专利授权号:ZL201210303288.0,专利授权日期:2015/07

 

 

主持教学改革项目

         1. 教育部产学合作协同育人项目左乙拉西坦原料药生产仿真实习,2022

         2. 第二批省级虚拟仿真一流实验教学课程,制药工程实验2021

         3. 校级课程思政示范课程,制药工程22022

         4. 校级专业核心课程,制药工程22021

         5. 校级线下一流课程,制药工程22020

 

主讲课程

本科生课程《制药工程学1》、《制药工程学2《制药工艺学》、《制药工程设计》、《制药工程安全与环保》、《药品生产质量管理规范》、《药事管理与法规》、《制药工程专业英语》、《过程设备机械设计基础》、《制药工程实验》、《化工原理实验》、《化工基础实验》虚拟仿真实验

研究生课程《现代化学化工进展》、《高等无机化学》、《分离工程》、《材料科学》

 

史重阳

制药工程专业,博士

联系方式:chongyangshi@ynnu.edu.cn

主要研究方向

过渡金属催化不对称合成;卡宾化学

主要招生专业

有机化学

教育与工作经历:

201709月~202106月,厦门大学 化学化工学院 博士学位

202107月~202209月,厦门大学 化学化工学院 博士后研究

202211至今          云南师范大学

代表性著作、论文、专利等

1. Chong-Yang Shi, Guang-Yu Zhu, Yin Xu, Ming-Yu Teng, Long-Wu Ye.* Recent Advances in Catalytic Asymmetric Büchner Reaction. Chin. Chem. Lett. 202334, in press.

2. Chong-Yang Shi, Bo Zhou, Ming-Yu Teng,* Long-Wu Ye.* Recent Advances in Asymmetric [1,2]-Stevens-Type Rearrangement via Metal Carbenes. Synthesis 202355, in press.

3. Chong-Yang Shi, Tao Han, Feng-Lin Hong, Long-Wu Ye,* Qing Sun,* Ming-Yu Teng.* Construction of Spirolactams by Unexpected Oxidative Cyclization of Alkenyl Diynes via Copper Catalysis. Org. Lett. 202325, 1525.

4. Chong-Yang Shi, Long-Wu Ye.* Asymmetric Construction of 3-Aminoindoline Skeleton Bearing N-α-Quaternary Carbon Center. Chin. J. Org. Chem. 202242, 4353. (invited highlight paper)

5. Chong-Yang Shi,‡ Ji-Jia Zhou,‡ Pan Hong,‡ Bo-Han Zhu, Feng-Lin Hong, Peng-Cheng Qian,* Qing Sun,* Xin Lu, Long-Wu Ye.* Efficient Synthesis of Tetracyclic γ-lactams via Gold-Catalyzed Oxidative Cyclization of Alkenyl Diynes. Org. Chem. Front. 20229, 2557.

6. Feng-Lin Hong,‡ Chong-Yang Shi,‡ Pan Hong, Tong-Yi Zhai, Xin-Qi Zhu, Xin Lu,* Long-Wu Ye.* Copper-Catalyzed Asymmetric Diyne Cyclization via [1,2]-Stevens-Type Rearrangement for the Synthesis of Chiral Chromeno[3,4-c]pyrroles. Angew. Chem. Int. Ed. 202261, e202115554.

7. Chong-Yang Shi, Long Li,* Wei Kang, Yan-Xin Zheng, Long-Wu Ye.* Claisen Rearrangement Triggered by Transition Metal-Catalyzed Alkyne Alkoxylation. Coord. Chem. Rev. 2021446, 214131.

8. Chao Shu,‡ Chong-Yang Shi,‡ Qing Sun, Bo Zhou, Tian-You Li, Qiao He, Xin Lu,* Rai-Shung Liu, Long-Wu Ye.* Generation of Endocyclic Vinyl Carbene Complexes via Gold-Catalyzed Oxidative Cyclization of Terminal Diynes: Towards Naphthoquinones and Carbazolequinones. ACS Catal. 20199, 1019.

9. Guang-Yu Zhu, Tong-Yi Zhai, Xiao LiChong-Yang Shi,* Xin-Qi Zhu, Long-Wu Ye.* Copper-Catalyzed Cyclization of N-Propargyl Ynamides with Borane Adducts through B–H Bond Insertion. Org. Lett. 202123, 8067.

10Hang-Hao Li, Yi-Ping Zhang, Tong-Yi Zhai, Bin-Yang LiuChong-Yang Shi,* Jin-Mei Zhou, Long-Wu Ye.* Metal-Free Dearomatization Reactions of Naphthol-Ynamides for Divergent and Enantioselective Synthesis of Azaspirocycles. Org. Chem. Front. 20229, 3709.

11Lin-Jun Qi, Chong-Yang Shi, Peng-Fei Chen, Long Li, Gang Fang, Peng-Cheng Qian,* Chao Deng,* Jin-Mei Zhou, Long-Wu Ye.* Gold-Catalyzed 1,1-Carboalkoxylation of Oxetane-Ynamides via Exocyclic Metal Carbenes: Divergent and Atom-Economical Synthesis of Tricyclic N-Heterocycles. ACS Catal. 202111, 3679.



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