我们在做有机反应时，经常会碰到一些非常重要的人名反应，但又不知道该反应的反应机理，所以我在这里整理了一下经常用到的反应机理。

        我们经常碰得比较多的是厦门大学的一个网站上的有机人名反应机理。链接地址：http://chem.xmu.edu.cn/teach/yjhx/onr/index.html

        还有一个比较全的是：The Merck Index—Organic Name Reaction

Organic Name Reactions

The Organic Name Reactions (ONR) section is intended to serve the professional chemist and student by describing organic chemical reactions which have come to be recognized and referred to by name within the chemistry community. A select group has been chosen for addition to this section. Each reaction description is designed to be informative and representative of the pertinent literature; however, it is not meant to be comprehensive. The descriptions are composed of the following: (1) name(s) associated with the reaction, (2) the original and/or primary contributor(s) connected with the discovery and/or development of the reaction, (3) a concise description of the transformation, (4) a reaction scheme, (5) key references, and (6) cross references to other ONR based on commonalities. The index included in this section also lists supplementary terms.

Abbreviations

Ac acetyl Ar aryl aq aqueous B base BBN borabicyclo[3.3.1]nonane BINAP 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl BOC t-butyloxycarbonyl Bu butyl cat catalytic Cp cyclopentyldienide Δ heat dba dibenzylideneacetone DCC dicyclohexylcarbodiimide DEAD diethylazadicarboxylate DME dimethylether dppf dichloro[1,1'-bis(diphenylphosphino)ferrocene] dppp 1,3-bis(diphenylphosphino)propane

E electrophile ee enantiomeric excess Et ethyl EtOH ethanol EWG electron withdrawing group HA protic acid HMPT hexamethylphosphoric triamide LDA lithium diisopropylamide LHMDS lithium hexamethyldisilazide Me methyl NuH nucleophile Ph phenyl Pr propyl salen N,N'-ethylenebis(salicylideneimine) Tf trifluoromethanesulfonyl Ts p-toluenesulfonyl

 下载地址：

The Merck Index—Organic Name Reaction

        最全的有机人名反应:The comprehensive E-book of named organic reactions and their mechanisms (2nd Edition)有机人名反应完整版(共1977页)

下载地址:

The comprehensive E-book of named organic reactions and their mechanisms (2nd Edition)有机人名反应完整版.part1.rar

The comprehensive E-book of named organic reactions and their mechanisms (2nd Edition)有机人名反应完整版.part2.rar

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