Abstract

Radiative thermoelectric energy converters, which include thermophotovoltaic cells, thermoradiative cells, electroluminescent refrigerators, and negative electroluminescent refrigerators, are semiconductor p-n devices that either generate electricity or extract heat from a cold body while exchanging thermal radiation with their surroundings. If this exchange occurs at micro or nanoscale distances, power densities can be greatly enhanced and near-field radiation effects may improve performance. This review covers the fundamentals of near-field thermal radiation, photon entropy, and nonequilibrium effects in semiconductor diodes that underpin device operation. The development and state of the art of these near-field converters are discussed in detail, and remaining challenges and opportunities for progress are identified.

Keywords

energy conversion systems, luminescent refrigeration, near-field radiation, thermophotovoltaic,thermoradiative cell 

摘要：作为半导体p-n装置，辐射热电能量转换器包括热光伏电池、热辐射电池、电致发光制冷机和负电致发光制冷机，可以在与周围环境进行热辐射交换时发电或者从冷源提取热量。如果当两个物体在微米或者纳米级的距离内进行热辐射交换时，热交换的能量密度可以被极大的增强，而且近场辐射效应可以提高工作性能。本综述主要涵盖了近场辐射基础理论、光子熵、半导体二极管中的非平衡态效应等支持装置操作的相关理论，详细讨论了这些近场转换器的发展以及现有技术，并且指出了面临的挑战和进一步发展的方向。

关键词：能量转换系统，发光制冷，近场辐射，热光电，热辐射电池

Abstract

As a class of newly emerging material, liquid metal exhibits many outstanding performances in a wide variety of thermal management areas, such as thermal interface material, heat spreader, convective cooling and phase change material (PCM) for thermal buffering etc. To help mold next generation unconventional cooling technologies and further advance the liquid metal cooling to an ever higher level in tackling more extreme, complex and critical thermal issues and energy utilizations, a novel conceptual scientific category was dedicated here which could be termed as combinatorial liquid metal heat transfer science. Through comprehensive interpretations on a group of representative liquid metal thermal management strategies, the most basic ways were outlined for developing liquid metal enabled combined cooling systems. The main scientific and technical features of the proposed hybrid cooling systems were illustrated. Particularly, five abstractive segments toward constructing the combinatorial liquid metal heat transfer systems were clarified. The most common methods on innovating liquid metal combined cooling systems based on this classification principle were discussed, and their potential utilization forms were proposed. For illustration purpose, several typical examples such as low melting point metal PCM combined cooling systems and liquid metal convection combined cooling systems, etc. were specifically introduced. Finally, future prospects to search for and make full use of the liquid metal combined high performance cooling system were discussed. It is expected that in practical application in the future, more unconventional combination forms on the liquid metal cooling can be obtained from the current fundamental principles.

Keywords

combinatorial heat transfer, liquid metal, high flux cooling, thermal management

摘要：作为一大类新兴的多功能材料，液态金属在热管理技术领域诸多方面均展现出优异的性能和巨大的应用前景，比如液态金属热界面材料、液态金属热展开器、液态金属对流冷却以及低熔点金属相变储能与热控技术等。为了指导下一代新型液态金属冷却技术的开发，以应对更加极端和复杂的冷却需求，这里，我们提出了液态金属组合传热学的概念。通过对典型的热管理技术的抽象划分和归纳总结，我们提炼出了一种构筑基于液态金属的复合式热管理技术的一般方法和原则，并就其中涉及到的关键科学问题和技术难点做了阐述。具体而言，可以将热管理系统抽象划分为五个环节，液态金属热管理技术可以根据应用场合的不同而在其中的一些主要环节中发挥关键性作用，从而实现与传统热管理技术的优势互补、取长补短，实现高性能高性价比的热管理技术方案。本文提出的液态金属组合传热学理念可望在构建新型复杂热管理系统和应对超常规极端冷却需求方面提供最基本的指导思路。

关键词：组合传热，液态金属，高通量冷却，热管理

Abstract

In the Leidenfrost state, the liquid drop is levitated above a hot solid surface by a vapor layer generated via evaporation from the drop. The vapor layer thermally insulates the drop from the heating surface, causing deteriorated heat transfer in a myriad of important engineering applications. Thus, it is highly desirable to suppress the Leidenfrost effect and elevate the Leidenfrost temperature. This paper presents a comprehensive review of recent literature concerning the Leidenfrost drops on micro/nanostructured surfaces with an emphasis on the enhancement of the Leidenfrost temperature. The basic physical processes of the Leidenfrost effect and the key characteristics of the Leidenfrost drops were first introduced. Then, the major findings of the influence of various micro/nanoscale surface structures on the Leidenfrost temperature were presented in detail, and the underlying enhancement mechanism for each specific surface topology was also discussed. It was concluded that multiscale hierarchical surfaces hold the best promise to significantly boost the Leidenfrost temperature by combining the advantages of both micro- and nanoscale structures.

Keywords

Leidenfrost drop, Leidenfrost temperature,     heat transfer enhancement,  micro/nanostructured surfaces

Abstract

Vibrational spectroscopy is one of the key instrumentations that provide non-invasive investigation of structural and chemical composition for both organic and inorganic materials. However, diffraction of light fundamentally limits the spatial resolution of far-field vibrational spectroscopy to roughly half the wavelength. In this article, we thoroughly review the integration of atomic force microscopy (AFM) with vibrational spectroscopy to enable the nanoscale characterization of emerging energy materials, which has not been possible with far-field optical techniques. The discussed methods utilize the AFM tip as a nanoscopic tool to extract spatially resolved electronic or molecular vibrational resonance spectra of a sample illuminated by a visible or infrared (IR) light source. The absorption of light by electrons or individual functional groups within molecules leads to changes in the sample’s thermal response, optical scattering, and atomic force interactions, all of which can be readily probed by an AFM tip. For example, photothermal induced resonance (PTIR) spectroscopy methods measure a sample’s local thermal expansion or temperature rise. Therefore, they use the AFM tip as a thermal detector to directly relate absorbed IR light to the thermal response of a sample. Optical scattering methods based on scanning near-field optical microscopy (SNOM) correlate the spectrum of scattered near-field light with molecular vibrational modes. More recently, photo-induced force microscopy (PiFM) has been developed to measure the change of the optical force gradient due to the light absorption by molecular vibrational resonances using AFM’s superb sensitivity in detecting tip-sample force interactions. Such recent efforts successfully breech the diffraction limit of light to provide nanoscale spatial resolution of vibrational spectroscopy, which will become a critical technique for characterizing novel energy materials.

Keywords

vibrational spectroscopy, atomic force microscopy,  photo-thermal induced resonance, scanning near-field optical microscopy, tip-enhanced Raman spectroscopy, photo-induced force microscopy, molecular resonances,  surface phonon polaritons,  energy materials

Abstract

Electrochemical energy storage is one of the few options to store the energy from intermittent renewable energy sources like wind and solar. Redox flow batteries (RFBs) are such an energy storage system, which has favorable features over other battery technologies, e.g. solid state batteries, due to their inherent safety and the independent scaling of energy and power content. However, because of their low energy-density, low power-density, and the cost of components such as redox species and membranes, commercialised RFB systems like the all-vanadium chemistry cannot make full use of the inherent advantages over other systems. In principle, there are three pathways to improve RFBs and to make them viable for large scale application: First, to employ electrolytes with higher energy density. This goal can be achieved by increasing the concentration of redox species, employing redox species that store more than one electron or by increasing the cell voltage. Second, to enhance the power output of the battery cells by using high kinetic redox species, increasing the cell voltage, implementing novel cell designs or membranes with lower resistance. The first two means reduce the electrode surface area needed to supply a certain power output, thereby bringing down costs for expensive components such as membranes. Third, to reduce the costs of single or multiple components such as redox species or membranes. To achieve these objectives it is necessary to develop new battery chemistries and cell configurations. In this review, a comparison of promising cell chemistries is focused on, be they all-liquid, slurries or hybrids combining liquid, gas and solid phases. The aim is to elucidate which redox-system is most favorable in terms of energy-density, power-density and capital cost. Besides, the choice of solvent and the selection of an inorganic or organic redox couples with the entailing consequences are discussed.

Keywords

electrochemical energy storage,redox flow battery,  vanadium    

Abstract

Composite materials, which consist of organic and inorganic components, are widely used in various fields because of their excellent mechanical properties, resistance to corrosion, low-cost fabrication, etc. Thermal properties of organic/inorganic composites play a crucial role in some applications such as thermal interface materials for micro-electronic packaging, nano-porous materials for sensor development, thermal insulators for aerospace, and high-performance thermoelectric materials for power generation and refrigeration. In the past few years, many studies have been conducted to reveal the physical mechanism of thermal transport in organic/inorganic composite materials in order to stimulate their practical applications. In this paper, the theoretical and experimental progresses in this field are reviewed. Besides, main factors affecting the thermal conductivity of organic/inorganic composites are discussed, including the intrinsic properties of organic matrix and inorganic fillers, topological structure of composites, loading volume fraction, and the interfacial thermal resistance between fillers and organic matrix.

Keywords

thermal conductivity, organic/inorganic composites, effective medium theory,  thermal percolation theory,interfacial thermal resistance   

Abstract

Recently, a solar thermal collector often employs nanoparticle suspension to absorb the solar radiation directly by a working fluid as well as to enhance its thermal performance. The collector efficiency of a direct absorption solar collector (DASC) is very sensitive to optical properties of the working fluid, such as absorption and scattering coefficients. Most of the existing studies have neglected particle scattering by assuming that the size of nanoparticle suspension is much smaller than the wavelength of solar radiation (i.e., Rayleigh scattering is applicable). If the nanoparticle suspension is made of metal, however, the scattering cross-section of metallic nanoparticles could be comparable to their absorption cross-section depending on the particle size, especially when the localized surface plasmon (LSP) is excited. Therefore, for the DASC utilizing a plasmonic nanofluid supporting the LSP, light scattering from metallic particle suspension must be taken into account in the thermal analysis. The present study investigates the scattering effect on the thermal performance of the DASC employing plasmonic nanofluid as a working fluid. In the analysis, the Monte Carlo method is employed to numerically solve the radiative transfer equation considering the volume scattering inside the nanofluid. It is found that the light scattering can improve the collector performance if the scattering coefficient of nanofluid is carefully engineered depending on its value of the absorption coefficient.

Keywords

direct absorption solar collector, plasmonic nanofluid,  light scattering

Abstract

The current research aims to present an inclusive review of latest research works performed with the aim of improving the efficiency of the hybrid renewable energy systems (HRESs) by employing diverse ranges of the optimization techniques, which aid the designers to achieve the minimum expected total cost, while satisfying the power demand and the reliability. For this purpose, a detailed analysis of the different classification drivers considering the design factors such as the optimization goals, utilized optimization methods, grid type as well as the investigated technology has been conducted. Initial results have indicated that among all optimization goals, load demand parameters including loss of power supply probability (LPSP) and loss of load probability (LLP), cost, sizing (configuration), energy production, and environmental emissions are the most frequent design variables which have been cited the most. Another result of this paper indicates that almost 70% of the research projects have been dedicated towards the optimization of the off-grid applications of the HRESs. Furthermore, it has been demonstrated that, integration of the PV, wind and battery is the most frequent configuration. In the next stage of the paper, a review concerning the sizing methods is also carried out to outline the most common techniques which are used to configure the components of the HRESs. In this regard, an analysis covering the optimized indicators such as the cost drivers, energy index parameters, load indicators, battery’s state of charge, PV generator area, design parameters such as the LPSP, and the wind power generation to load ratio, is also performed.

Keywords

hybrid renewable energy systems (HRESs),     design and optimization,environmental pollutions, PV array, wind turbines (WTs),      inverter,  diesel generator (DG) 

Abstract

Fuel cell vehicles, as the most promising clean vehicle technology for the future, represent the major chances for the developing world to avoid high-carbon lock-in in the transportation sector. In this paper, by taking China as an example, the unique advantages for China to deploy fuel cell vehicles are reviewed. Subsequently, this paper analyzes the greenhouse gas (GHG) emissions from 19 fuel cell vehicle utilization pathways by using the life cycle assessment approach. The results show that with the current grid mix in China, hydrogen from water electrolysis has the highest GHG emissions, at 3.10 kgCO₂/km, while by-product hydrogen from the chlor-alkali industry has the lowest level, at 0.08 kgCO2/km. Regarding hydrogen storage and transportation, a combination of gas-hydrogen road transportation and single compression in the refueling station has the lowest GHG emissions. Regarding vehicle operation, GHG emissions from indirect methanol fuel cell are proved to be lower than those from direct hydrogen fuel cells. It is recommended that although fuel cell vehicles are promising for the developing world in reducing GHG emissions, the vehicle technology and hydrogen production issues should be well addressed to ensure the life-cycle low-carbon performance.

Keywords

hydrogen,fuel cell vehicle, ife cycle assessment,energy consumption, greenhouse gas (GHG) emissions, China