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ACS Energy- Ni(HCO3)2 lithium ion battery 碳酸氢镍锂离子电池

已有 4645 次阅读 2016-12-14 08:46 |个人分类:我的文章|系统分类:论文交流| for, lithium, ion, battery, 碳酸氢镍

ACS Energy Lett., 2017, 2, pp 111–116
DOI: 10.1021/acsenergylett.6b00582
Publication Date (Web): December 9, 2016


Interconnected Ni(HCO3)2 Hollow Spheres Enabled by Self-Sacrificial Templating with Enhanced Lithium Storage Properties

Key Laboratory for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, PR China
School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, United States

Interconnectednickel bicarbonate (Ni(HCO3)2) hollow spheres were produced and exploited for the first time as an anode of lithiumion batteries, delivering the 80th reversible capacityof 1442 mAh g-1at the current rate of 100 mAg-1 which is 3.9 times the theoretical capacityof commercial anode graphite. The time-dependent study suggested a self-sacrificialtemplating formation mechanism that yielded such intriguing interconnectedhollow structures. X-ray photoelectron spectroscopy(XPS) measurements on cycled electrodes indicated thatboth the deep oxidation of Ni2+ into Ni3+ and thereversible reactions in HCO3- accounted for the ultrahighcapacity of Ni(HCO3)2in comparison to its generally accepted theoretical capacity of 297 mAh g-1. Morphological characterizations revealedthat the interconnected hollow structures enabled the enhancedrate performance and cycling stability due to their large contact areas with electrolyte andbetter buffering effect to accommodate the volume change compared to the solidcounterpart.


Ni(HCO3)2 for LIB-MS-ACS Energy Lett., 2017, 2, pp 111–116.pdf

Ni(HCO3)2 for LIB-SI-ACS Energy Lett., 2017, 2, pp 111–116.pdf


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