博文
钛改性MgO载体铑基催化剂甲烷部分氧化制氢
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Partial oxidation of methane towards hydrogen production over a promising class of catalysts: Rh supported on Ti-modified MgO
C. Mateos-Pedrero
, a, 
, C. Celliera, P. Eloya and P. Ruiza
aUnité de catalyse et chimie des matériaux divisés, Université catholique de Louvain, Croix du Sud 2/17, B-1348 Louvain-la-Neuve, Belgium
Available online 27 August 2007.
Abstract
The partial oxidation of methane over the supported Rh (0.8 wt.%) catalysts was investigated. Two kinds of supports were used, MgO and Ti-modified MgO (prepared by grafting technique). Among the Ti-modified MgO supports, two different compounds were used as source of Ti: inorganic (chloride) and organic (alkoxide). The catalytic performance of Rh-supported catalysts depends on the support and varies in the sequence: Ti-MgO/I > Ti-MgO/O > MgO. Ti-containing catalysts exhibited higher activity and selectivity compared to MgO, which is especially noticeable at low temperature. Possible explanations for the phenomena observed were proposed on the basis of characterization results.
https://blog.sciencenet.cn/blog-3913-13506.html
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