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Email:tcao@chem.ruc.edu.cn
电话:010-62514332
教授课程:目前讲授本科生《高分子化学》以及研究生《功能高分子》等课程。
主要研究领域:
i. 高分子材料的制备、组装及其功能化
ii. 非传统微纳米图案化技术的开发及其在生物、化学传感及能源器件上的应用。
Iii. 基于驻极体(Electrets)材料的超分子组装
科研项目:目前主持国家自然科学基金面上项目“在驻极体上构筑有序分子组装体系”以及“非传统方法制备超精细纳米结构及其应用”,并参与国家自然科学基金重点项目“基于超精细结构的集成微流芯片检测新方法”,主持教育部新世纪优秀人才计划项目。
近年来发表的代表性论文:
1. Mianqi Xue, Xinlei Ma, Zhuang Xie, Liting Duan, Yuqian Jiang, Meining Zhang and Tingbing Cao*, Fabrication of Au-based Conducting Polymer Nanoarrays for High-Performance Gas Sensor Applications, Chemistry,- An Asia Journal, 2010, 5, 2266.
2. Yiheng Zhang, Dan Zhao, Xinxin Tan, Tingbing Cao*, Xi Zhang*, AFM Force Mapping for Characterizing Patterns of Electrostatic Charges on SiO2 Electrets, Langmuir, 2010, 26, 11958.
3. Xinlei Ma, Dan Zhao, Mianqi Xue, Hai Wang, Tingbing Cao*, Selective discharge of electrostatics using a patterned hydrogel stamp, Angew. Chem. Int. Ed., 2010, 49, 5537.
Dan Zhao, Liting Duan, Mianqi Xue, Wei Ni, Tingbing Cao*, Patterning of Electrostatic Charge on Electrets Using Hot Microcontact Printing, Angew. Chem. Intl. Ed., 2009, 48, 6699.
Zhuang Xie, Liting Duan, Yuqian Jiang, Mianqi Xue, Meining Zhang, Tingbing Cao*, Thinner is better: ultrathin conducting oligoaniline film for gas microsensors with ultralow detection limit, Macromol. Rapid Commun. 2009, 30, 1589.
6. Mianqi Xue, Zhen Zhang, Nan Zhu, Fangfang Wang, Xin Sheng Zhao, Tingbing Cao*, Transfer printing of metal nanoparticles with controllable dimensions, placement and reproducible SERS effects, Langmuir, 2009, 25, 4347.
7. Fangfang Wang, Mianqi Xue, Tingbing Cao*, Thermo-chemically patterning of polymer film with tunable size reductions using metal-coated PDMS stamps, Adv. Mater., 2009, 21, 2211.
8. Mianqi Xue, Yang Zhang, Yanlian Yang, Tingbing Cao*, processing matters: the in-situ fabrication of conducting-polymer microsensors enables ultra-low-limit gas detection, Adv. Mater., 2008, 20, 2145.
9. Mianqi Xue, yanlian yang, Tingbing Cao*, Well positioned metallic nanostructures fabricated by nanotransfer edge printing, Adv. Mater., 2008, 20, 596.
10. Tingbing Cao, Qiaobing Xu, Adam Winkleman, George M. Whitesides, Fabrication of thin, metallic films along the sidewalls of pattered stamp and its application in charge printing, Small,2005, 1, 1191.
11. Byron D Gates, Qiaobing Xu, Venkat R Thalladi, Tingbing Cao, Knickerbocker Tanya, George M Whitesides, Shear patterning of microdominos: a new class of procedures for making micro- and nanostructures. Angewandte Chemie International Edition, 2004, 43, 2780.
12. Tingbing Cao, Fang Wei, Xiaoming Jiao, Jinyu Chen, Wei Liao, Xinsheng Zhao, Weixiao Cao, Micropatterns of protein and conducting polymer molecules fabricated by layer-by-layer self-assembly and photolithography techniques. Langmuir, 19, 8127, 2003.
13. Tingbing Cao, Fang Wei, Yanlian Yang, Lan Huang, Xinsheng Zhao, Weixiao Cao, Microtribologic properties of a covalently attached nanostructured self-assembly film fabricated from fullerene carboxylic acid and diazoresin. Langmuir, 18, 5186, 2002.
14. Tingbing Cao, Shuming Yang, Jie Cao, Maofeng Zhang, Chunhui Huang, Weixiao Cao, Nanoassembly film of carboxylic polyaniline with photosensitive diazoresin and its photoelectric conversion properties, Journal of Physical Chemistry B, 2001, 105, 11941.
曹廷炳课题组在非传统图案化技术方面取得新进展
http://chem.ruc.edu.cn/shouye/ShowArticle.asp?ArticleID=123
近年来,大面积的有序金属纳米图案化由于其在光电、传感、等离子共振等领域的广泛应用受到化学研究者的极大关注。在国家自然科学基金委以及中国人民大学的支持下,化学系曹廷炳教授领导的功能高分子器件课题组在非传统微纳米图案化加工研究领域取得的系列研究的基础之上,发展出一种新型制备有序金属图案化技术——有机蒸汽辅助制备金属微纳米结构。这种既简单又便宜的制备金属微纳米图案的方法,综合利用金属薄膜沉积,有机蒸汽溶胀硅橡胶模板,转移印刷这几种技术。基于硅胶模板在不同溶剂中的溶胀,使得在硅胶表面沉积的金属薄膜裂开,将裂开的金属薄膜转移到硅或者柔性基底上,从而成功地实现了金属薄膜的可控断裂,并在室温下操作得到大面积、可控、高精度图案化的微纳米结构,这种结构具有等离子共振效应,已经被成功应用于有机发光二极管(OLED)和表面增强拉曼(SERS)。 这种方法有望应用于下一代光电子器件,尤其是柔性电子器件。该研究成果发表在国际顶级化学期刊《德国应用化学》(Angew. Chem. Int. Ed., DOI: 10.1002/anie.201106490)。
不同溶剂调控金属纳米图案的紫外吸收光谱
制备有序金属纳米图案的示意图以及金属纳米的OLED和SERS图
链接:http://onlinelibrary.wiley.com/doi/10.1002/anie.201106490/abstract
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