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云师大物电学院张伟斌、朱挺在硅酸盐top期刊《Ceramics International》发表最新研究成果

已有 731 次阅读 2024-11-17 22:54 |个人分类:云师大研究|系统分类:论文交流

2024年11月12日，Elsevier 旗下top期刊《Ceramics International》在线发表了云南师范大学物理与电子信息学院张伟斌、朱挺团队的最新研究成果《Experimental and calculation investigations of the photocatalytic selective and performance for CO2 reduction by cobalt-doped Bi4O5Br2 nanosheets》。云南师范大学物理与电子信息学院张伟斌、朱挺为共同通讯作者。

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https://www.sciencedirect.com/science/article/abs/pii/S0272884224052453

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Abstract

This study delves into the photocatalytic process of an innovative Co-doped Bi4O5Br2 material synthesized through a straightforward process. Experimental and theoretical findings corroborate that cobalt doping remarkably enhances the CO2 reduction capability of Bi4O5Br2 catalysts under visible light. Findings indicate that Co-doped Bi4O5Br2 exhibits substantial advantages over its pristine counterpart in photocatalytic CO2 reduction. Notably, the catalyst with 4 at.% Co doping demonstrates the highest photocatalytic CO2 reduction efficiency, achieving CO and methane production activities of up to 9.46 and 0.20 μmol/g/h, respectively. Furthermore, the low activation energy for CO2 reduction in Co-doped Bi4O5Br2, as indicated by reaction pathways calculations, facilitates the process. Detailed experimental results reveal that Co incorporation does not alter the surface morphology or the crystalline phase of the photocatalyst. The superior efficiency of Co-doped Bi4O5Br2 is attributed to multiple factors: a narrow band gap, expanded visible light absorption spectrum, greater absorption intensity within the visible range, and enhanced separation efficiency of photogenerated electrons and holes compared to pristine Bi4O5Br2. This highlights the practical application of Co-doped Bi4O5Br2 for enhancing photocatalytic performance, supporting future advancements in solar energy utilization and the creation of high-value chemical products.