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标题: Aqueous charge injection: solvation bonding dynamics, molecular nonbond interactions, and solute extraordinary capabilities
https://www.tandfonline.com/doi/abs/10.1080/0144235X.2018.1544446
74 k words, 478 references, 79 figures, 21 tables
Synopsis:
DPS resolves the fraction and stiffness transition of O:H–O bonds from the mode of ordinary water to their hydration, which reconciles the phonon lifetime, surface stress, solution viscosity, molecular diffusivity, bonding thermodynamics, solution temperature, phase boundary dispersion, critical pressures and temperatures for phase transition, etc.
Keywords:
aqueous charge injection; molecular nonbond interactions; solvation bonding dynamics; extraordinary solute capabilities; DPS; anti-HB; super-HB; viscosity; surface stress; bond transition; ultrafast IR spectroscopy
Highlight:
O:H, H-H, O:=:O or ionic or dipolar polarization govern aqueous molecular interactions
Bond-nonbond cooperative relaxation and transition dictates the performance of a solution
DPS resolves O:H—O bond transition from the mode of ordinary water to hydration shells.
Amplifying surface and interface to atomic scale solvation and confinement is fascinating.
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