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从氢键非对称弛豫的角度出发,我们通过理论解析预测、实验测量分析、量子计算等方法系统定量地证明并阐述了水的十个秘密的物理起源及它们之间的内在关联,业已正式发表:
1. 姆潘巴佯谬: 热水比冷水结冰快(阿里斯托德,公元前350年)
2. 浮冰现象:冰的密度为何低?(伽利略,1613)
3. 复冰现象:210兆帕压强使冰的熔点降低22度(Regelation-Faraday-1859.pdf)
4. 表皮超固态Ice friction.pdf:冰润滑和水表皮的张力 (法拉第,1859年)
5. 霍夫梅斯特效应:盐离子调制水的表面张力和对蛋白质溶解能力(1888年)
6. 氢键质子对称:受压(X相)及冰的低压缩率(Holzapfel,1972年)
7. 协同过冷过热:纳米尺度水滴及气泡的力学热学稳定性
8. 尺度构形密度:水的单相四配位表皮超固态(高弹性,高熔点,强极化,疏水,自润滑,低密度)
9. 密度声子震荡:四温区氢键分段比热非对称导致水的效应
10.非对称超短程氢键作用势谱图的采集与绘制
11.氢键记忆效应(弛豫线速度与初始能量状态相关)
12.水桥water bridge (Willim Armstrong, 1893) (http://mysteriousuniverse.org/2014/09/think-you-know-everything-about-water-well-you-dont/)
敬请批评和补充新题目!多谢!
参考文献:
1. C.Q. Sun, et al, Density, Elasticity,and Stability Anomalies of Water Molecules with Fewer than Four Neighbors.J. Phys. Chem.Lett., 2013. 4:2565-2570.
2. C.Q. Sun,et al, Density and phonon-stiffness anomalies of water and ice in the fulltemperature range. J. Phy. Chem. Lett., 2013. 4: 3238-3244.
3. C.Q. Sun, X. Zhang, andW.T. Zheng, Hidden force opposing icecompression. Chem Sci, 2012. 3:1455-1460.
4. X. Zhang, et al, A common superslid skin covering both water and ice. PCCP, 2014:DOI: 10.1039/C1034CP02516D.
5. X. Zhang, et al, Hydrogen-bond memory and water-skin supersolidity resolving Mpembaparadox. PCCP, 2014: DOI: 10.1039/C1034CP03669G.
6. Y. Huang, et al Size, separation, structure order, and mass density of moleculespacking in water and ice. Sci. Rep., 2013. 3: 3005.
7. Y. Huang, et al, Hydrogen-bondasymmetric local potentials in compressed ice. J. Phys. Chem. B, 2013. 117: 13639-13645.
8. X. Zhang and C.Q. Sun, Hofmeister effect: Mediating hydrogen-bondrelaxation and water-skin tension by NaCl salting and heating. PCCP, 2014:Revised with minus modification.
9.Y. Huang, et al, Hydrogen-bond relaxation dynamics: Resolving mysteries of water ice. Coord Chem Rev, 2014: in press.
10. C.Q. Sun, Relaxation of the Chemical Bond. Springer Ser. Chem. Phys. Vol. 108. 2014 Berlin: Springer press; ISBN: 978-981-4585-20-0. 807 pages.
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