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学习经历
1. 2001.10 - 2005.10:博士(有机光电子),香港大学化学系及电机电子工程系(导师支志明C. M. Che院士& P. T. Lai教授);
2. 1997.9 - 2000.7:硕士(分析化学),厦门大学化学系(导师王尊本教授 & 赵一兵教授);
3. 1993.9 - 1997.7:学士(化学,国家教育部人才基地班),厦门大学化学系。
工作经历
1. 2014.7 -至今:研究员、博士生导师(有机金属配合物高功能材料及应用),四川大学化学学院;
2. 2009.7 -2014.9:副教授(有机金属配合物高功能材料及器件),四川大学化学学院;
3. 2009.7 - 2012.7:荣誉助理教授(Honorary Assistant Professor),香港大学化学系;
4. 2005.11 - 2009.6:博士后(Postdoc Research Fellow,有机&无机高功能材料及电子器件),香港大学化学系及电机电子工程系 [导师支志明院士 & P. T. Lai教授];
5. 2000.9 - 2001.8:研究助理(Research Assistant,光化学及光物理),香港大学化学系(导师支志明院士);
主要研究方向 有机发光材料
主要工作业绩
师从于支志明院士(Prof. C. M. Che,香港大学化学系),现工作于四川大学化学学院。本人在有机发光材料方面有多年研究经验,研究成果发表于Chem. Soc. Rev.、J. Am. Chem. Soc.、 Angew. Chem.Int. Ed.、Adv. Mater.和Chem. Eng. J.等国际知名学术期刊,并以第一作者身份参与撰写英文著作《Highly efficient OLEDs with phosphorescent materials》(Chapter 7,Wiley-VCH 2007),发表SCI文章90余篇,被引用4500余次,H因子37,ESI高引用论文3篇。个人网站:https://blog.sciencenet.cn/home.php?mod=space&uid=581887。
主要学术贡献:
(1)构建新型配位引起的面手性及其人名命名“Xiang and Song”(J. Am. Chem. Soc. 2022, 144, 2233、Angew. Chem. Int. Ed. 2023, 62, e2023020和Inorg. Chem. 2023, 62, 14152);
(2)构建首例“点线面螺”手性分子(Inorg. Chem. 2023, 62, 14152);
(3)首次发现消旋导致发光增强现象(Dalton Trans. 2019, 48, 4420);
(4)首次提出手性打破分子对称和电荷平衡分布,增强分子内电荷转移(ICT)或D-A体系的理论(Dyes Pigments 2022, 197, 109906、J. Phys. Chem. Lett. 2022, 13, 5838和Sci. China Chem. 2024, DOI: 10.1007/s11426-024-2124-3)。
代表性成果 (获奖成果、专著、论文、专利)
10篇代表论文:
1. 构建首例“点线面螺”全手性分子:W. Y. Yun, L. Qu, B. Zhang, Q. P. Yang, J. T. Song, X. G. Zhou, H. F. Xiang,* ““Point-line-plane-helix” binuclear platinum(II) complexes: metal-induced chirality, chirality self-sorting, and chiroptical properties”, Inorg. Chem. 2023, 62, 14152 (封面).
2. 基于软桥联配体的面手性双核Pt(II)配合物:J. T. Song,* H. Xiao, B. Zhang, L. Qu, X. G. Zhou, P. Hu, Z. X. Xu,* H. F. Xiang,* “Metal-induced planar chirality of soft-bridged binuclear platinum(II) complexes: 100% phosphorescence quantum yields, chiral self-sorting, and circularly polarized luminescence”, Angew. Chem. Int. Ed. 2023, 62, e202302011.
3. 基于轴手性联苯吩恶嗪的热激活延迟荧光(TADF):L. Qu, H. Xiao, B. Zhang, Q. P. Yang, J. T. Song, X. G. Zhou, Z. X. Xu*, and H. F. Xiang,* “Axially chiral biphenoxazine-based thermally activated delayed fluorescence materials for solution-processed circularly polarized organic light-emitting diodes”, Chem. Eng. J. 2023, 471, 144709.
4. 罗丹明染料分子的圆偏振发光开关、手性自分选和细胞成像的研究:L. Qu, X. M. Zhou, J. T. Song, B. Zhang, Q. P. Yang, X. G. Zhou, J. Liu,* H. F. Xiang,* “Circularly polarized luminescence switching, chirality self-sorting, and cell imaging of chiral rhodamine Dyes”, Adv. Optical Mater. 2023, 11, 2300779.
5. 构建金属配位引起的新型面手性双核Pt(II)配合物及其在CP-OLEDs中的应用:J. T. Song, H. Xiao, L. Z. Fang, L. Qu, X. G. Zhou, Z. X. Xu,* C. Yang,* H. F. Xiang,* “Highly phosphorescent planar chirality by bridging two square-planar platinum(II) complexes: chirality induction and circularly polarized luminescence”, J. Am. Chem. Soc. 2022, 144, 2233.
6. 超纯轴手性双咔唑室温磷光:J. T. Song, Y. Y. Wang, L. Qu, L. Z. Fang, X. G. Zhou, Z. X. Xu,* C. Yang,* P. Wu,* H. F. Xiang,* “Room-temperature phosphorescence of pure axially chiral bicarbazoles”, J. Phys. Chem. Lett. 2022, 13, 5838.
7. 基于联萘和还原联萘的双核Pt(II)配合物及其在CP-OLEDs中的应用:L. Wang, H. Xiao, L. Qu, J. T. Song, W. L. Zhou, X. G. Zhou, H. F. Xiang,* Z. X. Xu,* “Axially chiral bis-cycloplatinated binaphthalenes and octahydro-binaphthalenes for efficient circularly polarized phosphorescence in solution-processed organic light-emitting diodes”, Inorg. Chem. 2021, 60, 13557.
8. 基于轴手性螺旋结构的螺吡喃固态分子光开关:L. Qu, X. M. Xu, J. T. Song, D. H. Wu, L. Wang, W. L. Zhou, X. G. Zhou, and H. F. Xiang,* “Solid-state photochromic molecular switches based on axially chiral and helical Spiropyrans”, Dyes Pigments 2020, 181, 108597.
9. 简单、可视、高选择性的手性识别超分子凝胶:X. M. Xu, L. Qu, J. T. Song, D. H. Wu, X. G. Zhou, and H. F. Xiang,* “Simple and visual approach for enantioselective recognition through supramolecular gels with specific selectivity”, Chem. Commun., 2019, 55, 9873.
10. 近红外磷光材料及应用综述:H. F. Xiang,* J. H. Cheng, X. F. Ma, X. G. Zhou, and J. J. Chruma, “Near-infrared phosphorescence: materials and applications”, Chem. Soc. Rev., 2013, 42, 6128.
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