2024年5月20日，Elsevier 旗下top期刊《Water Research》在线发表了云南师范大学物理与电子信息学院张伟斌博士最新研究成果《Ultrathin BiOCl-OV/CoAl-LDH S-scheme heterojunction for efficient photocatalytic peroxymonosulfate activation to boost Co (IV)=O generation》。云南师范大学物理与电子信息学院张伟斌博士和中国地质大学（北京）陈代梅为论文共同通讯作者。

https://www.sciencedirect.com/science/article/pii/S0043135424006754

Abstract

Sustainable and rapid production of high-valent cobalt-oxo (Co(IV)=O) species for efficiently removing organic pollutants is challenging in permoxymonosulfate (PMS) based advanced-oxidation-processes (AOPs) due to the limitation of the high 3d-orbital electronic occupancy of Co and slow conversion from Co(III) to Co(II). Herein, S-scheme BiOCl-OV/CoAl-LDH heterojunction were constructed by ultrathin BiOCl with the oxygen-vacancy (OV) self-assembled with ultrathin CoAl-LDH. OV promoted the formation of charge transfer channel (Bi-O-Co bonds) at the interface of the heterojunction and reduced electron occupation of the Co 3d-orbital to facilitate the generation of Co(IV)=O in the BiOCl-OV/CoAl-LDH/PMS/Visible-light system. S-scheme heterojunction accelerated the photogenerated electrons to allow rapid conversion of Co(III) to Co(II), promoting the fast two-electron transfer from Co(II) to Co(IV)=O. Consequently, the developed BiOCl-OV/CoAl-LDH/PMS/Visible-light system showed excellent degradation efficiency for most of organic pollutions, and exhibited very high removal capability for the actual industrial wastewater. This study provides a new insight into the evolution of Co(IV)=O and the coordinative mechanism for photocatalysis and PMS activation.

扩展阅读：

云师大张伟斌博士与加拿大滑铁卢大学工程学院吴义民(YiMin WU）教授合作在国际著名《SMALL》上发表最新研究成果

云师大张伟斌博士与加拿大滑铁卢大学合作在国际著名《Materials Today Physics》发表最新研究成果

云师大张伟斌博士与中国地质大学（北京）陈代梅团队合作在国际著名《化学工程杂志》发表最新研究成果

张伟斌

https://wdxy.ynnu.edu.cn/info/1080/1938.htm

【基本情况】张伟斌，云南师范大学物理与电子信息学院副教授，硕士生导师。长江大学领军人才，云南师范大学高层次人才。获得国家自然科学基金和湖北省自然科学基金各一项；第一作者或者通信作者发表SCI论文33篇，中国科学院一区、二区10篇，其中一篇论文连续2020,2021,2022年入选ESI高被引论文，为全球前1%热点科研论文。先后获得中国驻韩国大使馆颁发的2014,2016年度全韩优秀公派生。

2013年9月-2017年8月 韩国东国大学 公派攻读固体物理学博士学位

2009年9月-2012年7月 四川大学 光学硕士学位

2004年9月-2008年7月 乐山师范学院 物理学

【研究方向】

• 低维纳米材料的合成、表征

• 新材料的机器学习筛选和理论研究

• 光催化/热催化处理污染气体（NO气体去除，CO2还原为有机燃料等）

• 太阳能光伏电池的设计和试验研究

【教学经历】

2014年9月-2017年1月 韩国东国大学物理系 助教

2017年9月-2019年12月 长江大学物理与光电工程学院 讲师

2019年12月-2021年12月 长江大学物理与光电工程学院 副教授

2022年1月-至今 云南师范大学物理与电子信息学院 副教授

研究生课程：《纳米材料物理》《功能材料设计》《固体理论》

本科生课程：《太阳能光伏技术》《LED封装及应用》《半导体薄膜技术》《光电工程实训》《大学物理实验》

主持编撰长江大学留学生理论物理学培养方案（中/英双语）。

【近几年的学术研究】

1.承担的学术研究课题

国家自然科学基金：低维g-C3N4/Bi4O5Br2材料的电子结构、光学及电子输运性质的理论研究，主持

湖北省自然科学基金：3d过渡金属掺杂二维g-C3N4/Bi4O5Br2新型光催化材料的可控构建及性能研究，主持

MoS2/Graphene 杂化结构的合成与应用研究 韩国国家自然科学基金 助研

国防重点科研项目：太赫兹量子阱级连激光器的设计和研究 助研

2.指导硕士生5名

唐梅（获得国家奖学金），张欣欣，孙志远，许静，Nsajigwa Mwankemwa（国家留学基金委资助），张玉梅

【国内外公开发表的学术论文（一作或者通信作者）】

JCR-Q1 JCR一区一共20篇，一作或通信:

1.Yi Xiao, Chen Shen,Weibin Zhang*，Screening and Prediction of Metal Doped α-borophene Monolayer for Nitric Oxide Elimination,Materials Today Chemistry, Materials Today Chemistry 25 (2022) 100958 (IF: 8.30, JCR一区，中国科学院一区) 10.1016/j.mtchem.2022.100958.

2.Nsajigwa Mwankemwa, Hong-En Wang, Ting Zhu, Qiang Fan, Fuchun Zhang,Weibin Zhang*, First principles calculations investigation of optoelectronic properties and photocatalytic CO2 reduction of (MoSi2N4)5-n/(MoSiGeN4)n in-plane heterostructures, Results in Physics 37 (2022) 105549.

3.Zhiyuan Sun, Jin Xu, Nsajigwa Mwankemwa, Shanjun Chen,Weibin Zhang*,Alkali-metal(Li, Na, and K)-adsorbed MoSi2N4 monolayer: an investigation of its outstanding electronic, optical, and photocatalytic properties,Communications in Theoretical Physics, 74(2022),015503.

4.JingNing, Jin Zhang,Weibin Zhang*, Junfeng Yan*, Fuchun Zhang*, Experiment and DFT study on the photocatalytic properties of La-doped Bi2WO6 nanoplate-like materials, Applied Surface Science,579,2022,152219

5.Jing Xu, Qingfeng Wu, Nsajigwa Mwankemwa,Weibin Zhang*,Wenxing Yang, First-principles investigations of electronic, optical, and photocatalytic properties of Au-adsorbed MoSi2N4monolayer, Journal of Physics and Chemistry of Solids 162 (2022) 110494.(IF:3.99,JCR一区)

6.Xiaomin Hou, Qi Cheng, Jianrong Wang, Qingfeng Wu*,Weibin Zhang*,Combinedfirst-principles calculations andexperimental study on the photocatalyticmechanism of natural dolomite, RSC advances, 2021, 11, 24416-24423.

7.Yang-Yang Guo* ,Wei-Bin Zhang*, Yan-Ni Yang , Cheng Wang,The photocatalytic efficiency enhancement of Bi4O5Br2by Li-intercalation for NO removal,Journal of Physics and Chemistry of Solids 159 (2021) 110256.(IF:3.99,JCR一区)

8.Yucheng Ou, Gangqiang Zhu*, Fei Rao,Weibin Zhang*, Coral-Shaped TiO2−δDecorated with Carbon Quantum Dots and Carbon Nanotubes for NO Removal, ACS Applied Nano Materials,2021, 4, 7330-7342(IF: 5.09,中国科学院一区)

9.NsajigwaMwankemwa,Weibin Zhang*, Desheng Zhu,First-principles calculations to investigate the electronic and optical properties of (MoS2)4-n/(MoSSe)nlateral heterostructure,Journal of Physics and Chemistry of Solids,154,2021, 110049.(IF:3.99,JCR一区)

10.WeibinZhang*, Yi Xiao*,Mechanism of Electrocatalytically Active Precious Metal (Ni, Pd, Pt, and Ru) Complexes in the Graphene Basal Plane for ORR Applications in Novel Fuel Cells, Energy & Fuels, 2020, 34(2), 2425-2434(IF:3.61,被引用41次，JCR一区, 2020，2021，2022年度工程类ESI高被引)

11.WeibinZhang,Xun Xiao,Qing-Feng Wu,Qiang Fan,Shanjun Chen, Wen-Xing Yang,Fu-Chun Zhang,Facile synthesis of novel Mn-doped Bi4O5Br2 for enhanced photocatalytic NO removal activity,Journal of Alloys and Compounds 826 (2020) 154204.(IF:5.32,被引用41次，JCR一区，中国科学院二区)

12.WeibinZhang, Zhijun Zhang, Fuchun Zhang, Boandoh Stephen, Kwun-Bun Chung,WoochulYang,Photocatalytic improvement of Mn-adsorbedg-C3N4, Applied Catalysis B: Environmental, 206 (2017) 271-281. (IF:19.51,JCR一区top，被引用60次，中国科学院一区)

13.WeibinZhang,Zhijun Zhang, WoochulYang, Facile enhancement of photocatalytic efficiency of g-C3N4by Li-intercalation, Catalysis Today,321-322(2019), 67-73. (IF:6.77,JCR一区，中国科学院二区)

14.Weibin Zhang, Yi Wang, Jianrong Wang, Yi Xiao, Theoretical prediction of the structural, electronic, mobility, and dynamic properties of Mo3N2T2(T = H, O and OH) with Li adsorption feature, Solid State Ionics 325 (2018) 238–246 (IF:3.78,JCR一区)

15.WeibinZhang,Zhijun Zhang, Fuchun Zhang,WoochulYang, Ti-decorated graphitic-C3N4monolayer: A promising material for hydrogen storage, Applied Surface Science, 386, 2016, 247-254.(IF:6.71,JCR一区，中国科学院一区)

16.Yi Xiao, Jianrong Wang, Yi Wang,Weibin Zhang*,A new promising catalytic activity on blue phosphorene nitrogen-doped nanosheets for the ORR as cathode in nonaqueous Li–air batteries, Applied Surface Science, 2019, 488, 620-628.(IF:6.71,JCR一区，中国科学院一区)

17.Wei Wang,Junfeng Yan, Fuchun Zhang,Weibin Zhang*, Experimental and DFT investigation on the different effects of Er3+- and Ag+ -doped BiOBr microspheres in enhancing photocatalytic activity under visible light irradiation, Journal of Materials Science 2020, 55 (25) 11226-11240.(IF:4.22,JCR一区，中国科学院二区)

18.Wei Wang,Junfeng Yan, Fuchun Zhang,Weibin Zhang*,Weihu Zhang, Magnetic and optical properties of Co-doped ZnO nanorod arrays, European Physical Journal Plus, 2020, 135:40.(IF: 3.91，JCR一区)

19.Fuchun Zhang, Dandan Chao, Hongwei Cui, Weihu Zhang,Weibin Zhang*, Electronic structure and magnetism of Mn-doped ZnO nanowires. Nanomaterials, 2015,5, 885-894.(IF:5.01,JCR一区，中国科学院二区)

20.Hong Sheng, Wei Wang, Rong Dai, Jing Ning, Lei Zhang, Qiao Wu, Fuchun Zhang*, andWeibin Zhang*,New Insights into Cd2+/Fe3+Co-Doped BiOBr for Enhancing the Photocatalysis Efficiency of Dye Decomposition under Visible-Light,Nanomaterials 2021, 11, 423 (IF:5.01,JCR一区，中国科学院二区)

二区、三区、四区：

21.Yi Xiao,Weibin Zhang*,High-Throughput Calculation Investigations on the Electrocatalytic Activity of Codoped Single Metal–Nitrogen Embedded in Graphene for ORR Mechanism, Electrocatalysis, 2020(11), 393-404. (IF 2.58，JCR二区)

22.Mei Tang, Fuchun Zhang, Shanjun Chen, Song Li,Weibin Zhang*,First principles investigation of the stability and electronic properties of fluorinated Janus MoSSe Monolayer. Journal of Theoretical and Computational Chemistry, 18, 2019, 1950024.

23.Xinxin Zhang, Yi Song, Fuchun Zhang, Long Jiang,Weibin Zhang*, The electronic properties of hydrogenated Janus MoSSe monolayer: a first principles investigation, Materials Research Express, 6, 2019, 105055.

24.Zhang Weibin,YangWoochul,The hydrogen adsorption on Zr-decorated LiB (001): A DFT study, Vacuum, 110, 2014, 62-68. (IF: 2.067,三区SCI，Times Cited: 3)

25.Zhang Weibin，YangWoochul, Stability and electronic properties of hydrogenated MoS2monolayer: a first-principles study, Journal of Nanoscience and Nanotechnology, 15, 2015, 8075-8080. (IF: 1.354,三区SCI，Times Cited: 3)

26.Weibin Zhang, Shanjun Chen, Gangqiang Zhu,Yonghong Tian,Woochul Yang, Fuchun Zhang, Qingfeng Wu, Enhanced Photocatalytic Properties of Bi4O5Br2by Mn doping:A First Principles Study, Materials Research Express, 2018, 5(7): 075512~075512 (IF: 1.92,四区SCI，被引用：1次)

27.Weibin Zhang, Gangqiang Zhu, Woochul Yang, Shanjun Chen, Fuchun Zhang, Fe-doped Bi4O5Br2Visible Light Photocatalyst: A First Principles Investigation, Journal of Theoretical and Computational Chemistry, 2018, 17(5): 1850031~1850031

28.Zhang Weibin,YangWoochul, First principle calculation the electronic structure and the optical properties of Mn-Decoratedg-C3N4for photocatalytic applications, Journal of Korean Physical Society, 69, 2016, 1445-1449. (IF: 0.45,四区SCI)

29.Zhang Weibin, Wu Weidong, Cheng Xinlu, Wang Xuemin, NbO2and Nb2O5Investigation of Electronic structure by XPS, UPS and first principles methods, Surface and Interface Analysis,45,2013, 1206-1210.( IF: 1.02,四区SCI, Times Cited: 54)

30.Zhang Weibin,Woochul Yang, First principles study of Ti-catalyzed hydrogen adsorption on LiB (001) surface, Journal of Theoretical & Computational Chemistry, Vol.12,No.7 (2013) 1350065.

31.Zhang Weibin, Wu Weidong, Cheng Xinlu, Wang Xuemin, Wang Haiping, An Xinyou, H2adsorption on LiB (001) surface: A first principles calculation,Journal of Theoretical & Computational Chemistry, Vol.11,No.4 (2012) 781-790. (Times Cited: 3)

32.Fuchun Zhang,Rui Chen, Weihu Zhang,Zhang Weibin*, ATi-decorated boron monolayer: a promising material for hydrogen storage, RSC Adv., 2016, 6, 12925-12931 (IF: 2.936,三区SCI)

33.Fuchun Zhang, Liu Yang,Zhang Weibin*, The first principles study of hydrogen adsorption on Ni decorated LiB(001) surface. Chin. Phys. Lett., 32, 2015, 057302.(IF: 0.87,4区SCI)

34.孙志远，唐梅，Nsajigwa Mwankemwa,张伟斌*，Li掺杂单层Janus MoSSe电子结构和光学性质的第一性原理研究，广西师范大学学报，2021.02.03网络首发，10.16088/j.issn.1001-6600.2020100601， 中文核心。

35.Qiao Wu, Rong Dai, Lei Zhang, Wei Wang, Fuchun Zhang*, andWeibin Zhang*,Theoretical Study of a Novel Infrared NonlinearOptical Crystal of BaGa4S7, Journal of Nanoelectronics and Optoelectronics, 2020,15(11):1395-1405

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