刘柏平，男，1966年3月出生，祖籍湖南平江。华东理工大学特聘教授,博士生导师

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  【主要教学科研成果】       2） 在菲利浦铬系聚乙烯催化合成机理中，首先发现了乙烯易位反应活性中心在聚合诱导期中的形成机理及其向乙烯聚合活性中心的转换机理。该成果已在催化领域核心 杂志J. Mol. Catal. A Chem.上发表。 被Chem. Rev.（第105卷，第1期，第159页）评价该发现为对烯烃配位聚合引发机理认识的重要突破。该全新机理的发现使对乙烯聚合机理有了更深的认识,并对 实用铬系催化剂的设计和开发提供了理论指导。

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    3） 在聚烯烃高分子纳米复合材料领域，首次发现了纳米粒子对聚烯烃高分子材料结晶过程中球晶生长的抑制作用，而且发现当纳米粒子之间的平均距离达到或小于高分 子链两末端平均距离时，高分子在结晶时将不会形成球晶，从而得到完全透明的高分子纳米复合材料，开创了一种利用纳米技术合成透明的半结晶性高分子纳米复合 材料的通用方法，该发现为高分子纳米复合材料领域的重大理论突破, 并具有重大的应用前景。成果最近已在高分子领域著名杂志Macromol.Rapid Commun.和Polymer上发表。

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 【研究方向】       主要学科方向为工业催化、聚合反应工程、高分子化学与物理、固体表面物理化学、计算化学和纳米复合材料合成等多学科交叉领域。主要研究课题方向如下。     1. 聚烯烃多相催化合成机理的研究以及分子模拟     2. 新型烯烃聚合催化剂的开发与设计     3. 基于催化剂和聚合反应工程的新型聚烯烃高分子材料的开发与设计     4. 基于聚烯烃的纳米复合材料以及聚烯烃纳米复合材料的功能化     5. 环境友好的烯烃聚合绿色工艺催化剂核心技术的开发     6. 聚烯烃材料及其纳米复合材料的氧化降解机理以及长寿命化和循环利用     7. 新型生物酶（包括金属酶）催化技术       热诚欢迎报考本研究室的硕士、博士研究生或联系博士后、访问学者等。  

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【通信地址】   上海市梅陇路 130 号华东理工大学化工学院，邮编： 200237； 电话: 021-64253627，传真: 021-64253159; Email: boping@ecust.edu.cn
http://hgxy.ecust.edu.cn/_siteid/11/pageid/14/columnid/856/articleid/1911/displayinfo.htm 【论文发表情况】   近年（2001-至今）代表性论文： [P-1]. W. Sun, B. Liu (SCI). Organometallics (Book Review), Macromol. Chem. and Phys. 207, 2006, 1416. [P-2]. K. Nitta, K. Asuka, B. Liu, M. Terano, Polymer 2006, 47, 6457-6463. (SCI). The Effect of the Addition of Silica Particles on Linear Spherulite Growth Rate of Isotactic Polypropylene and its Explanation by Lamellar Cluster Model   [P-3]. B. Liu, H. Matsuoka, M. Terano, Macromol. Rapid Commun. 2001, 22, 1-24. (SCI). Stopped-Flow Techniques in Ziegler Catalysis   [P-4]. H. Matsuoka, B. Liu, H. Nakatani, M. Terano Macromol. Rapid Commun. 2001, 22, 326-328. (SCI). Variation in the Isospecific Active Sites of Internal Donor-Free MgCl2-Supported Ziegler Catalysts: Effect of External Electron Donor   [P-5]. K. Asuka, B. Liu, M. Terano, K. Nitta, Macromol. Rapid Commun. 2006, 27, 910-913. (SCI). Homogeneously Dispersed Polypropylene/SiO2 Nanocomposites with Unprecedented Transparency   [P-6]. Y. Fang, B. Liu, K. Hasebe, M. Terano, J. Polym. Sci. Part A: Polym. Chem. 2005, 43, 4632-4641. (SCI). Ethylene and 1-Hexene Copolymerization with CO-Prereduced Phillips CrOx/SiO2 Catalyst in the Presence of Al-alkyl Cocatalyst   [P-7]. Y. Fang, B. Liu, M. Terano, Appl. Catal. A: General, 2005, 279, 131-138. (SCI). Photo-Stability of Surface Chromate Species on Phillips CrOx/SiO2 Catalysts Isothermally Calcined at Various Temperatures Probed by High Resolution XPS Method   [P-8]. B. Liu, M. Terano, J. Mol. Catal. A: Chem. 2001, 172, 227-240. (SCI). Investigation of the Physico-Chemical State and Aggregation Mechanism of Surface Cr Species on a Phllips CrOx/SiO2 Catalyst by XPS and EPMA   [P-9]. B. Liu, H. Nakatani, M. Terano, J. Mol. Catal. A: Chem. 2002, 184, 387-398. (SCI). New Aspects of the Induction Period of Ethene Polymerization using Phillips CrOx/SiO2 Catalyst Probed by XPS, TPD and EPMA   [P-10]. B. Liu, H. Nakatani, M. Terano, J. Mol. Catal. A: Chem. 2003, 201, 189-197. (SCI). Mechanistic Implications of the Unprecedented Transformations of Ethene into Propene and Butene over Phillips CrOx/SiO2 Catalyst During Induction Period   [P-11]. B. Liu, K. Fukuda, H. Nakatani, I. Nishiyama, M. Yamahiro, M. Terano, J. Mol. Catal. A: Chem. 2004, 219, 363-370. (SCI). 27Al MAS Solid State NMR Study on Coordinative Nature of Alkyl-Al Cocatalysts on a Novel SiO2-Supported Ziegler-Natta Catalyst for Controlled Multiplicity of Molecular Weight Distribution   [P-12]. B. Liu, Y. Fang, M. Terano, J. Mol. Catal. A: Chem. 2004, 219, 165-173. (SCI). High Resolution XPS Analysis for Isothermal Transformation of Surface Chromium (III) species into Supported Chromate Species on Various Calcined Phillips CrOx/SiO2 Catalysts   [P-13]. B. Liu, P. ?indelá?, Y. Fang, K. Hasebe, M. Terano, J. Mol. Catal. A: Chem. 2005, 238, 142-150. (SCI). Correlation of Oxidation States of Surface Chromium Species with Ethylene Polymerization Activity for Phillips CrOx/SiO2 Catalysts Modified by Al-Alkyl Cocatalyst   [P-14]. W. Xia, B. Liu, Y. Fang, K. Hasebe, M. Terano, J. Mol. Catal. A: Chem. 2006, 256, 301-308.(SCI). Unique Polymerization Kinetics Obtained from Simultaneous Interaction of Phillips Cr(VI)Ox/SiO2 Catalyst with Al-Alkyl Cocatalyst and Ethylene Monomer   [P-15]. T. Nitta, B. Liu, H. Nakatani, M. Terano, J. Mol. Catal. A: Chem. 2002, 180, 25-34. (SCI). Formation, Deactivation and Transformation of Stereospecific Active Sites on TiCl4/Dibutylphthalate/Mg(OEt)2 Catalyst Induced by Short Time Reaction with Al-alkyl Cocatalyst   [P-16]. Y. Fang, W. Xia, M. He, B. Liu, K. Hasebe, M. Terano, J. Mol. Catal. A: Chem. 2006, 247, 240-247. (SCI). Novel SiO2-Supported Chromium Catalyst Bearing New Organo-Siloxane Ligand for Ethylene Polymerization   [P-17]. K. Fukuda, B. Liu, H. Nakatani, I. Nishiyama, M. Yamahiro and M. Terano, Catal. Commun. 2003, 4, 657-662. (SCI). Significant Variation of Molecular Weight Distribution (MWD) of Polyethylene Induced by Different Alkyl-Al Co-Catalysts Using a Novel Surface Functionalized SiO2-Supported Ziegler-Natta Catalyst   [P-18]. B. Liu, T. Nitta, H. Nakatani, M. Terano, Macromol. Chem. Phys. 2002, 203, 2412-2421. (SCI). Specific Roles of Al-Alkyl Cocatalyst in the Origin of Isospecificity of Active Sites on Donor-Free TiCl4/MgCl2 Ziegler-Natta Catalyst   [P-19]. B. Liu, T. Nitta, H. Nakatani, M. Terano, Macromol. Chem. Phys. 2003, 204, 395-402. (SCI). Stereospecific Nature of Active Sites on TiCl4/MgCl2 Ziegler-Natta Catalyst in the Presence of an Internal Electron Donor   [P-20]. Q. Wang, N. Murayama, B. Liu, M. Terano, Macromol. Chem. Phys. 2005, 206, 961-966. (SCI). Effects of Electron Donor on Active Sites Distribution of MgCl2-Supported Ziegler-Natta Catalysts Investigated by Multiple Active Sites Model   [P-21]. B. Liu, N. Murayama and M. Terano, Ind. Eng. Chem. Res. 2005, 44, 2382-2388. (SCI). Transformation of　Polymerization Sites into Hydrogen Dissociation Sites on Propylene Polymerization Catalyst Induced by the Reaction with Al-Alkyl Cocatalyst   [P-22]. B. Liu, Y. Fang, M. Terano, Mol. Simulat. 2004, 30, 963-971. (SCI). Theoretical Study of the Monomer Reaction Mechanism on Phillips CrOx/SiO2 Catalyst Using Density Functional Theory (DFT) and Paired Interacting Orbitals (PIO) Methods   [P-23]. T. Higuchi, B. Liu, H. Nakatani, N. Otsuka, M. Terano, Appl. Surf. Sci. 2003, 214, 272-277. (SCI). High Resolution Transmission Electron Microscope Observation of -TiCl3   [P-24]. N. Manabe, K. Kawamura, M. Ishikawa, S. Suzuki, B. Liu, M. Terano and H. Nakatani Polymer Testing, 2005, 24, 994-997. (SCI). Development of a Novel Potentiometric Titration Method for Determination of Polypropylene Degradation   [P-25]. N. Murayama, B. Liu, H. Nakatani, M. Terano, Polym. Int. 2004, 53, 723-727. (SCI). Plausible Guard Effect on the Active Sites of Heterogeneous Ziegler-Natta Catalyst by Coordinating Monomers and Growing Polymer Chains in the Initial Stage of Propylene Polymerization   [P-26]. H. Matsuoka, B. Liu, H. Nakatani, I. Nishiyama, M. Terano, Polym. Int. 2002, 51, 781-784. (SCI). Active Sites Deterioration of MgCl2-Supported Catalyst Induced by the Electron Donor Extraction by Alkylaluminium   [P-27]. Y. W. Shin, H. Nakatani, T. Uozumi, B. Liu, T. Sano, K. Nitta, M. Terano, Polym. Int. 2003, 52, 29-34. (SCI). Stepwise polymerization of propylene and ethylene with Cr(acac)3/MgCl2-EB/DEAC catalyst system   [P-28]. Q. Wang, Y. Lin, Z. Zhang, B. Liu, M. Terano, J. Appl. Polym. Sci. 2006, 100, 1978-1982. (SCI). High Temperature Polymerization of Propylene Catalyzed by MgCl2-Supported Ziegler-Natta Catalysts with Various Cocatalysts   [P-29]. C. Huo, X. Ren, B. Liu, Y. Yang, S. Rong, J. Appl. Polym. Sci. 2003, 90, 1463-1470. (SCI). Fractal Approach for Modeling the Morphology Evolution of Olefin Polymerization with Heterogeneous Catalysts   [P-30]. M. S. Alam, H. Nakatani, B. G. S. Goss, T. Ichiki, B. Liu, M. Terano, J. Appl. Polym. Sci. 2002, 86, 1863-1867. (SCI). Improvement of the Photostability of Isotactic Polypropylene by the Incorporation of Ethylene   [P-31]. N. Manabe, Y. Yokota, H. Nakatani, S. Suzuki, B. Liu, M. Terano, J. Appl. Polym. Sci. 2006, 100, 1831-1835. (SCI). Local Thermal Oxidative Degradation Behavior of Heterophasic Polypropylene Impact Copolymer   [P-32]. S. Suzuki, B. Liu, M. Terano, N. Manabe, K. Kawamura, M. Ishikawa, H. Nakatani, Polym. Bull. 2005, 55, 141-147. (SCI). Influence of Primary Structure on Thermal Oxidative Degradation of Polypropylene Impact Copolymer   [P-33]. S. Suzuki, Y. Nakamura, ATM K. Hasan, B. Liu, M. Terano and H. Nakatani, Polym. Bull. 2005, 54, 311-319. (SCI). Dependence of Tacticity Distribution in Thermal Oxidative Degradation of Polypropylene   [P-34]. N. Manabe, Y. Yokota, H. Nakatani, S. Suzuki, B. Liu, M. Minoru, Polym. Bull. 2005, 54, 141-145. (SCI). Study of Local Oxidative Degradation in Polypropylene Impact Copolymer by Energy Dispersive X-Ray System   [P-35]. ATM K. Hasan, B. Liu, M. Terano, Polym. Bull. 2005, 54, 225-236. (SCI). Effects of Various Preparation and Polymerization Conditions on the Isospecific Nature of Polypropylene Catalysts   [P-36]. I. Nishiyama, B. Liu, H. Matsuoka, H. Nakatani, M. Terano, Macromol. Symp. 2003, 193, 71-80. (SCI). Kinetic Evaluation of Various Isospecific Active Sites on MgCl2-supported Ziegler Catalysts   [P-37]. M. Terano, B. Liu, H. Nakatani, Macromol. Symp. 2004, 214, 299-306. (SCI). New Approaches for the Development of Highly Stable Polypropylene   [P-38]. B. Liu, Y. Fang, H. Nakatani, M. Terano, Macromol. Symp. 2004, 213, 37-46. (SCI). Surface Physico-Chemical State of CO-Prereduced Phillips CrOx/SiO2 Catalyst and Unique Polymerization Behavior in the Presence of Al-Alkyl Cocatalyst   [P-39]. B. Liu, H. Matsuoka, M. Terano, Macromol. Symp. 2001, 165, 3-10. (SCI). Kinetic Investigation of Propene Polymerization with Stopped-Flow Method   [P-40]. B. Liu, T. Nitta, H. Nakatani, M. Terano, Macromol. Symp. 2004, 213, 7-18. (SCI). Precise Arguments on the Distribution of Stereospecific Active Sites on MgCl2-Supported Ziegler-Natta Catalysts   [P-41]. Y. Fang, B. Liu, M. Terano, Kinet. Catal. 2006, 47, 295-302. (SCI). Various Activation Procedures of Phillips Catalyst for Ethylene Polymerization   [P-42]. B. Liu, Y. Fang, Wei Xia, M. Terano, Kinet. Catal. 2006, 47, 234-240. (SCI). Theoretical Investigation of Novel Silsesquioxane-Supported Phillips Type Catalyst by Density Functional Theory (DFT) Method   [P-43]. B. Liu, W. Xia, M. Terano, Stud. Surf. Sci. Catal. 2006, 161, 129-134. (SCI). Computational Approach on the Interaction Between CrO3 and Ethylene as a Model for the Understanding of Phillips Catalyst   [P-44]. W. Xia, B. Liu, Y. Fang, D. Zhou, M. Terano, Stud. Surf. Sci. Catal. 2006, 161, 225-228. (SCI). Plausible mechanism for the formation and transformation of active sites on novel Phillips type catalyst with new organo-siloxane ligand   [P-45]. A. Shiga, B. Liu, M. Terano, Stud. Surf. Sci. Catal. 2006, 161, 219-224. (SCI). Theoretical Study on Active Site Formation of Olefin Metathesis and Olefin Polymerization in Phillips CrOx/SiO2 Catalyst by PIO Analysis   [P-46]. K. Asuka, I. Kouzai, B. Liu, M. Terano, K. Nitta, Stud. Surf. Sci. Catal, 2006, 161, 237-240.(SCI). Effects of silica particles on the transparency of polypropylene based nanocomposites   [P-47]. K.Sumino, K. Asuka, B. Liu, M.. Yamaguchi, M. Terano, T. Kawamura, K. Nitta, Stud. Surf. Sci. Catal, 2006, 161, 229-232.(SCI). Influence of Polymer Morphology on the Photo-Stability of Polypropylene/SiO2 Nanocomposites   [P-48]. M. Terano, M. Yamahiro, H. Kono, H. Nakatani, B. Liu, Abstr. Pap. Am. Chem. Soc. 221: 381, Part 2, Apr. 1, 2001. (SCI). Synthesis of Novel Olefin Block Copolymer by Stopped-Flow Polymerization Method and Its Application for Investigation of Stereospecific Active Sites on MgCl2-Supported Ziegler Catalyst   [P-49]. M. Terano, B. Liu, Y. Fang, Polymer Preprints, ACS, 2003, 44(2), 22-23. (SCI). New Proposal on the Branching Mechanism of Phillips CrOx/SiO2 Catalyst for Ethylene Homo-Polymerization    

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相关新闻

华东理工大学特聘教授刘柏平来我中心进行技术交流

2007 年1月18日，中国石油兰州化工研究中心在院二楼会议室，华东理工大学刘柏平教授来我中进行技术交流，中心领导赵旭涛、朱博超及兰州化工研究中心从事聚烯 烃领域研究的负责人及相关人员参加了此次交流活动，双方对石油兰州化工研究中心从事聚烯烃领域内催化剂载体及催化剂的制备方面的一些关键性问题进行了探 讨。 刘柏平，1966年3月出生，祖籍湖南平江，1996年12月获工学博士学位, 1999年5月至2005年11月期间在日本国立北陆先端科学技术大学院大学材料科学系、日本国立北陆科学技术大学院大学材料科学系特任副教授、瑞士联邦 理工大学化学与应用生物科学系Michele Parrinello教授研究室、意大利Naples大学化学系Vincenzo Busico教授实验室等地做访问学者；2006年9月-至今华东理工大学化工学院教授华东理工大学特聘教授,博士生导师，共发表学术论文110于篇，申 请日本发明专利一项。多次参与承办聚烯烃工业催化国际学术会议，应邀作大会邀请报告7次和特邀报告4次。 中石油化工研究院兰州化工研究中心从2000年小试研究自今，经过不断的努力，现已建成80t/a年产硅胶中试装置一套，完成硅胶在工业装置上的应用评价 试验，无论从物性指标还是其他性能显示，国产化的硅胶已达到甚至超过国外同类硅胶产品。下一步，硅胶将逐步在国内大型工业装置上的试应用，完成此类硅胶的 国产化。 会上，华东理工大学的刘柏平教授做了题为《硅胶负载型聚烯烃催化剂硅胶的核心作用》的报告。报告首先介绍了今年来国内有关聚烯烃方面的发展及装置建设情 况，阐述了硅胶作为催化剂载体对于催化剂性能及制备得到聚合物各种性能的影响，并结合刘教授多年在铬系催化剂方面的研究，用具体实验数据表明载体对聚合物 性能影响的重要程度，并对兰州化工研究中心在催化剂载体—硅胶制备方面所取得的成绩给予了充分的肯定，对于我中心所制硅胶在工业化实验所取得的成果给予了 热烈的祝贺！ 兰州化工研究中心的领导对刘教授的报告及工作给与了充分了肯定，并希望在下一步的工作中就有关双方共同关心的话题进行进一步的合作交流。

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