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【催化牛人简介】张绪穆——不对称催化
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【催化牛人简介】张绪穆——不对称催化
Phone: (732) 445-1489
Dept: (732) 445-2618
Office: WR-211
Email：xumu@rutgers.edu
个人主页： http://rutchem.rutgers.edu/~xumuweb/
Mail: Chemistry & Chemical Biology, 610 Taylor Road, Piscataway, NJ 08854
教育背景：
* B.S. in Chemistry, Wuhan University, Hubei, The People’s Republic of China, 1982
* M.S. in Physical and Inorganic Chemistry, Chinese Science Academy, Fuzhou, the People’s Republic of China, 1985
* M.S. in Organometallic Chemistry, University of California, San Diego, CA, 1987
* Ph. D. in Organic and Inorganic Chemistry, Stanford University, Stanford, CA, 1992
* Postdoctoral and Research Associate, Department of Chemistry, Stanford University, Stanford, CA, 1992-1994
* M.S. in Physical and Inorganic Chemistry, Chinese Science Academy, Fuzhou, the People’s Republic of China, 1985
* M.S. in Organometallic Chemistry, University of California, San Diego, CA, 1987
* Ph. D. in Organic and Inorganic Chemistry, Stanford University, Stanford, CA, 1992
* Postdoctoral and Research Associate, Department of Chemistry, Stanford University, Stanford, CA, 1992-1994
* Assistant Professor of Organic Chemistry, Department of Chemistry, The Pennsylvania State University, University Park, PA, 1994-1999
* Associate Professor of Organic Chemistry, Department of Chemistry, The Pennsylvania State University, University Park, PA, 1999-2003
* Professor of Organic Chemistry, Department of Chemistry, The Pennsylvania State University, University Park, PA, 2003-2006
* Professor of Organic Chemistry, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, NJ, 2007
研究方向：
Synthetic organic, inorganic and organometallic chemistry, transition metal catalyzed asymmetric reactions for the synthesis of biologically active compounds, biomimetic chemistry, molecular recognition and material chemistry.
成果及获奖情况：
* Franklin Veatch Graduate Fellowship, 1991, Stanford University
* The Camille and Henry Dreyfus Foundation New Faculty Award, 1994
* DuPont Young Faculty Award, 1996
* Office of Naval Research Young Investigator Award, 1996
* The Camille and Henry Dreyfus Foundation Teacher-Scholar Award, 1998
* The John Simon Guggenheim Foundation Fellow, 2000
* The Outstanding Oversea Chinese Young Scientist B, Chinese Academy of Sciences, 2000
* The Penn State Faculty Scholar Medal, 2001
* The Young Innovation Award of ChiTec (Chinese High Tech) in Chemistry, 2001
* The American Chemical Society Arthur C. Cope Scholar Award, 2002
* The SDCA (San Diego Chinese Association) Achievement Award, 2002
近期发表论文：
- 2006 -
(83) " Chiral bisphospholane ligands (Me-ketalphos): synthesis of their Rh(I) complexes and applications in asymmetric hydrogenation" Dai, Q.; Wang, C.-J.; Zhang, X. Tetrahedron 2006, 62, 868-871.
(84) " Highly enantioselective hydrogenation of N-phthaloyl enamides" Yang, Q.; Gao, W.; Deng, J.; Zhang, X. Tetrahedron Lett. 2006, 47, 821-823.
(85) " Six-membered bis(azaphosphorinane), readily available ligand for highly enantioselective asymmetric hydrogenations" Yan, Y.; Zhang, X. Tetrahedron Lett. 2006, 47, 1567-1569.
(86) " Highly enantioselective Ru-catalyzed hydrogenation of b-keto esters using electron-donating bis(trialkylphosphine) ligand-TangPhos" Wang, C.-J.; Tao, H.; Zhang, X. Tetrahedron Lett. 2006, 47, 1901-1903.
(87) " Triazole-Based Monophosphine Ligands for Palladium-Catalyzed Cross-Coupling Reactions of Aryl Chlorides" Dai, Q.; Gao, W.; Liu, D.; Kapes, L. M.; Zhang, X. J. Org. Chem. 2006, 71, 3928-3934.
(88) " (h5-Triphenylindenyl)Ru(CO)2Cl: A New Ruthenium Catalyst for the Highly Efficient Racemization of Chiral 1-Phenylethanol at Room Temperature" Xi, Q.; Zhang, W.; Zhang, X. Synlett 2006, 945-947.
(89) " Highly Enantioselective Hydrogenation of a-Keto Esters Catalyzed by Ru-Tunephos Complexes" Wang, C.-J.; Sun, X.; Zhang, X. Synlett 2006, 1169-1172.
(90) " A Highly Enantioselective, Pd-TangPhos-Catalyzed Hydrogenation of N-Tosylimines" Yang, Q.; Shang, G.; Gao, W.; Deng, J.; Zhang, X. Angew. Chem. Int. Ed. 2006, 45, 3832-3835.
(91) " A Hybrid Phosphorus Ligand for Highly Enantioselective Asymmetric Hydroformylation" Yan, Y.; Zhang, X. J. Am. Chem. Soc. 2006, 128, 7198-7202.
(92) " Synthesis of Triphosphorous Bidentate Phosphine-Phosphoramidite Ligands and their Application in Highly Enantioselective Hydrogenation of ortho-Substituted Aryl Enamides" Zhang, W.; Zhang, X. Angew. Chem. Int. Ed. 2006, 45, 5515-5518.
(93) " Rh-Catalyzed Asymmetric Hydrogenation of a-Aryl Imino Esters: An Efficient Enantioselective Synthesis of Aryl Glycine Derivatives" Shang, G.; Yang, Q.; Zhang, X. Angew. Chem. Int. Ed. 2006, 45, 6360-6362.
(94) " Asymmetric Hydrogenation of Pyridines: Enantioselective Synthesis of Nipecotic Acid Derivatives" Lei, A.; Chen, M.; He, M.; Zhang, X. Eur. J. Org. Chem. 2006, 45, 4343-4347.
(95) " A Tetraphosphorus Ligand for Highly Regioselective Isomerization-Hydroformylation of Internal Olefins" Yan, Y.; Zhang, X.; Zhang, X. J. Am. Chem. Soc. 2006, 128, 16058-16061.
(96) " Practical synthesis of chiral 9,9'-spirobixanthene-1,1'-diol" Zhang, W.; Wu, S.; Zhang, Z.; Yennawar, H.; Zhang, X. Org. Biomol. Chem. 2006, 4, 4474-4477.
- 2007 -
(97) " Highly Enantioselective Hydrogenation of a-Dehydroamino Esters and Itaconates with Triphosphorous Bidentate Ligands and the Unprecedented Solvent Effect Thereof" Zhang, W.; Zhang, X. J. Org. Chem. 2007, 72, 1020-1023.
(98) " Rh-Catalyzed Highly Enantioselective Synthesis of 3-Arylbutanoic Acids" Sun, X.; Zhou, L.; Wang, C.-J.; Zhang, X. Angew. Chem. Int. Ed. 2007, 46, 2623-2626.
转自麦兜
* Associate Professor of Organic Chemistry, Department of Chemistry, The Pennsylvania State University, University Park, PA, 1999-2003
* Professor of Organic Chemistry, Department of Chemistry, The Pennsylvania State University, University Park, PA, 2003-2006
* Professor of Organic Chemistry, Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, NJ, 2007
研究方向：
Synthetic organic, inorganic and organometallic chemistry, transition metal catalyzed asymmetric reactions for the synthesis of biologically active compounds, biomimetic chemistry, molecular recognition and material chemistry.
成果及获奖情况：
* Franklin Veatch Graduate Fellowship, 1991, Stanford University
* The Camille and Henry Dreyfus Foundation New Faculty Award, 1994
* DuPont Young Faculty Award, 1996
* Office of Naval Research Young Investigator Award, 1996
* The Camille and Henry Dreyfus Foundation Teacher-Scholar Award, 1998
* The John Simon Guggenheim Foundation Fellow, 2000
* The Outstanding Oversea Chinese Young Scientist B, Chinese Academy of Sciences, 2000
* The Penn State Faculty Scholar Medal, 2001
* The Young Innovation Award of ChiTec (Chinese High Tech) in Chemistry, 2001
* The American Chemical Society Arthur C. Cope Scholar Award, 2002
* The SDCA (San Diego Chinese Association) Achievement Award, 2002
近期发表论文：
- 2006 -
(83) " Chiral bisphospholane ligands (Me-ketalphos): synthesis of their Rh(I) complexes and applications in asymmetric hydrogenation" Dai, Q.; Wang, C.-J.; Zhang, X. Tetrahedron 2006, 62, 868-871.
(84) " Highly enantioselective hydrogenation of N-phthaloyl enamides" Yang, Q.; Gao, W.; Deng, J.; Zhang, X. Tetrahedron Lett. 2006, 47, 821-823.
(85) " Six-membered bis(azaphosphorinane), readily available ligand for highly enantioselective asymmetric hydrogenations" Yan, Y.; Zhang, X. Tetrahedron Lett. 2006, 47, 1567-1569.
(86) " Highly enantioselective Ru-catalyzed hydrogenation of b-keto esters using electron-donating bis(trialkylphosphine) ligand-TangPhos" Wang, C.-J.; Tao, H.; Zhang, X. Tetrahedron Lett. 2006, 47, 1901-1903.
(87) " Triazole-Based Monophosphine Ligands for Palladium-Catalyzed Cross-Coupling Reactions of Aryl Chlorides" Dai, Q.; Gao, W.; Liu, D.; Kapes, L. M.; Zhang, X. J. Org. Chem. 2006, 71, 3928-3934.
(88) " (h5-Triphenylindenyl)Ru(CO)2Cl: A New Ruthenium Catalyst for the Highly Efficient Racemization of Chiral 1-Phenylethanol at Room Temperature" Xi, Q.; Zhang, W.; Zhang, X. Synlett 2006, 945-947.
(89) " Highly Enantioselective Hydrogenation of a-Keto Esters Catalyzed by Ru-Tunephos Complexes" Wang, C.-J.; Sun, X.; Zhang, X. Synlett 2006, 1169-1172.
(90) " A Highly Enantioselective, Pd-TangPhos-Catalyzed Hydrogenation of N-Tosylimines" Yang, Q.; Shang, G.; Gao, W.; Deng, J.; Zhang, X. Angew. Chem. Int. Ed. 2006, 45, 3832-3835.
(91) " A Hybrid Phosphorus Ligand for Highly Enantioselective Asymmetric Hydroformylation" Yan, Y.; Zhang, X. J. Am. Chem. Soc. 2006, 128, 7198-7202.
(92) " Synthesis of Triphosphorous Bidentate Phosphine-Phosphoramidite Ligands and their Application in Highly Enantioselective Hydrogenation of ortho-Substituted Aryl Enamides" Zhang, W.; Zhang, X. Angew. Chem. Int. Ed. 2006, 45, 5515-5518.
(93) " Rh-Catalyzed Asymmetric Hydrogenation of a-Aryl Imino Esters: An Efficient Enantioselective Synthesis of Aryl Glycine Derivatives" Shang, G.; Yang, Q.; Zhang, X. Angew. Chem. Int. Ed. 2006, 45, 6360-6362.
(94) " Asymmetric Hydrogenation of Pyridines: Enantioselective Synthesis of Nipecotic Acid Derivatives" Lei, A.; Chen, M.; He, M.; Zhang, X. Eur. J. Org. Chem. 2006, 45, 4343-4347.
(95) " A Tetraphosphorus Ligand for Highly Regioselective Isomerization-Hydroformylation of Internal Olefins" Yan, Y.; Zhang, X.; Zhang, X. J. Am. Chem. Soc. 2006, 128, 16058-16061.
(96) " Practical synthesis of chiral 9,9'-spirobixanthene-1,1'-diol" Zhang, W.; Wu, S.; Zhang, Z.; Yennawar, H.; Zhang, X. Org. Biomol. Chem. 2006, 4, 4474-4477.
- 2007 -
(97) " Highly Enantioselective Hydrogenation of a-Dehydroamino Esters and Itaconates with Triphosphorous Bidentate Ligands and the Unprecedented Solvent Effect Thereof" Zhang, W.; Zhang, X. J. Org. Chem. 2007, 72, 1020-1023.
(98) " Rh-Catalyzed Highly Enantioselective Synthesis of 3-Arylbutanoic Acids" Sun, X.; Zhou, L.; Wang, C.-J.; Zhang, X. Angew. Chem. Int. Ed. 2007, 46, 2623-2626.
转自麦兜
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