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图文目录|GEE Volume 6, Issue 4

已有 1193 次阅读 2021-8-11 11:32 |系统分类:论文交流

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Green Energy & Environment 第六卷第四期已正式出版。本期共收录文章16篇,其中research highlight和review article各2篇,research paper12篇。部分文章中文解读已在微信公众号推送,欢迎阅读。其他文章中文详解将在近期推送,敬请关注~

*封面文章:云南大学方文浩教授团队研究论文:Performant Au hydrogenation catalyst cooperated with Cu-doped Al2O3 for selective conversion of furfural to furfuryl alcohol at ambient pressure。

封底文章:太原理工大学刘光副教授和李晋平教授团队研究论文:Amorphous iron-nickel phosphide nanocone arrays as efficient bifunctional electrodes for overall water splittinge。


图文目录

Research highlights

Microinterfacial technology enhancing mass transfer in chemical engineering

Suojiang Zhang*(张锁江)

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https://doi.org/10.1016/j.gee.2021.03.004


Cationic potential: An effective descriptor for rational design of layered oxides for sodium-ion batteries
Xudong Zhao, Li-Zhen Fan*(范丽珍), Zhen Zhou*(周震)

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https://doi.org/10.1016/j.gee.2020.11.022


Review articles

Recent advances in non-precious metal electrocatalysts for pH-universal hydrogen evolution reaction
Shen Zhang, Xing Zhang*(张星), Yuan Rui, Ruihu Wang, Xiaoju Li*(李小菊)

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Hydrogen evolution reaction (HER) is the cathodic half reaction in water splitting and chlor-alkali electrolysis. Versatile electrolyzer systems require cost-effective HER electrocatalysts to be operated under different pH conditions. This review summarized recent progresses in non-precious metal electrocatalysts for pH-universal HER. The methods for overcoming their activity/stability limitations are highlighted.

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https://doi.org/10.1016/j.gee.2020.10.013


Regulation of the photogenerated carrier transfer process during photo-electrochemical water splitting: A review
Yaping Zhang, Yuyu Bu*(补钰煜), Lin Wang, Jin-Ping Ao

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Photogenerated carrier’s regulation is a key technique to improve the performance of PEC water splitting. According to the different transfer processes of photogenerated carriers, several typical and efficient control strategies, such as doping, heterojunction, tandem structure and Z-scheme structure, have been analyzed and summarized in this review to raise more research attentions of this filed.

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https://doi.org/10.1016/j.gee.2020.11.007


Research papers

Amorphous iron-nickel phosphide nanocone arrays as efficient bifunctional electrodes for overall water splitting
Guang Liu*(刘光), Yun Wu, Rui Yao, Fei Zhao, Qiang Zhao, Jinping Li*(李晋平)

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Benefiting by the unique 3D morphology of nanocone arrays, the resultant FeP-Ni/NF demonstrates efficient catalytic activity towards the OER, HER as well as overall water splitting.

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https://doi.org/10.1016/j.gee.2020.05.009


Fe-Nx sites enriched microporous carbon nanoflower planted with tangled bamboo-like carbon nanotube as a strong polysulfides anchor for lithium–sulfur batteries

Hongtai Li, Yanxiao Chen, Quan Jin, Wei Xiang, Benhe Zhong, Xiaodong Guo*(郭孝东), Bao Wang*(王宝)

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With the assistance of VC, a sulfur host composed of Fe-Nx sites enriched flower-like microporous core along with bamboo-like carbon nanotubes shell was fabricated, which exhibits strong physicochemical confining capability of polysulfides for long cycling lithium-sulfur batteries.

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https://doi.org/10.1016/j.gee.2020.06.004


Rational architecture design of yolk/double-shells Si-based anode material with double buffering carbon layers for high performance lithium-ion battery

Zhenyu Wu, Jing Luo, Jiao Peng, Hong Liu, Baobao Chang, Xianyou Wang*(王先友)

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In this work, we have fabricated the yolk/double-shells (YDS) Si/C anode material with double buffering resin-based carbon layers, which was deliberately designed and fabricated by making use of HF to dissolve the SiO2 in intermediate layer. The unique architecture design with double buffering layers can provide a stable electrochemical stability at 0.5 A g-1 for 200 cycles.

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https://doi.org/10.1016/j.gee.2020.06.009


Development of a gaseous and solid-state hybrid system for stationary hydrogen energy storage

Haizhen Liu*(刘海镇), Li Xu, Yu Han, Xin Chen, Peng Sheng, Shumao Wang*(王树茂), Xiantun Huang, Xinhua Wang*(王新华), Chenglin Lu, Hui Luo, Shixuan He, Zhiqiang Lan, Jin Guo

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An advanced gaseous and solid-state (G-S) hybrid hydrogen storage system with a low working pressure below 5 MPa for a 10 kW hydrogen energy storage experiment platform is developed and validated.

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https://doi.org/10.1016/j.gee.2020.06.006


Construction of 2D/2D Z-scheme MnO2-x/g-C3N4 photocatalyst for efficient nitrogen fixation to ammonia

Limin Yu, Zhao Mo, Xianglin Zhu, Jiujun Deng, Fan Xu, Yanhua Song*(宋艳华), Yuanbin She, Huaming Li, Hui Xu*(许晖)

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This work presented here provided a new example of preparing 2D g-C3N4 composites modified by ultrathin sheet MnO2-x as nitrogen fixation photocatalyst which achieved ammonia yield of 225 μmol g-1 h-1 (1 wt% MnO2-x/2D g-C3N4).

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https://doi.org/10.1016/j.gee.2020.05.011


Performant Au hydrogenation catalyst cooperated with Cu-doped Al2O3 for selective conversion of furfural to furfuryl alcohol at ambient pressure
Junjie Chen1, Weixiao Sun1, Yongxing Wang, Wenhao Fang*(方文浩)

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Au NPs (3 nm) loaded on Lewisacidic-basic Cu-doped Al2O3 efficiently hydrogenated furfural to furfuryl alcohol in liquid phase at ambient pressure using i-PrOH and H2 as proton donors.

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https://doi.org/10.1016/j.gee.2020.05.005


Competition between acidic sites and hydrogenation sites in Cu/ZrO2 catalysts with different crystal phases for conversion of biomass-derived organics

Yuewen Shao, Tingting Wang, Kai Sun, Zhanming Zhang, Lijun Zhang, Qingyin Li, Shu Zhang, Guangzhi Hu*(胡广志), Xun Hu*(胡勋)

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Monoclinic zirconia supported copper catalyst with fewer acidic sites exhibited superior activity for the conversion of furfural and vanillin to the targeting products rather than the by-products catalyzed by acidic sites.

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https://doi.org/10.1016/j.gee.2020.05.007


Highly active and stable Co nanoparticles embedded in nitrogen-doped mesoporous carbon nanofibers for aqueous-phase levulinic acid hydrogenation

Shuai Shao, Ying Yang*(杨英), Shangwei Guo, Shijie Hao, Feng Yang, Suoying Zhang, Yang Ren, Yangchuan Ke*(柯扬船)

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The Co catalyst with metallic Co and Co-Nx dual active sites embedded in mesoporous carbon nanofibers exhibits outstanding aqueous-phase levulinic acid hydrogenation activity and excellent durability.

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https://doi.org/10.1016/j.gee.2020.11.005


Recyclable polymer functionalization via end-group modification and block/random copolymerization

Yihuan Liu, Jiaqi Wu, Huan Liang, Zhao Jin, Lianzhu Sheng, Xin Hu, Ning Zhu*(朱宁), Kai Guo*(郭凯)


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End-group functionalized poly ((R)-3,4-trans six-membered ring-fused GBL) and block/random copolymers containing ε-caprolactone, l-lactide and trimethylene carbonate were investigated by employing di-n-butylmagnesium as the catalyst.

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https://doi.org/10.1016/j.gee.2020.06.003


Nanocomposite membranes with high-charge and size-screened phosphorylated nanocellulose fibrils for CO2 separation

Ragne Marie Lilleby Helberg, Jonathan Ø. Torstensen, Zhongde Dai, Saravanan Janakiram, Gary Chinga-Carrasco, Øyvind W. Gregersen, Kristin Syverud, Liyuan Deng*(邓立元)


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Thin-film nanocomposite membranes were fabricated, showing significantly improved CO2 separation performance by incorporating surface-modified cellulose nanofibrils (CNF) of high charge (H-P-CNF) and screened size (H-P-CNF-S) into a PVA matrix, especially under humidified conditions.

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https://doi.org/10.1016/j.gee.2020.08.004


Trail of sulfur during the desulfurization via reactive adsorption on Ni/ZnO
Ye Song1, Bo Peng1, Xue Yang, Qiuqiao Jiang, Jun Liu, Wei Lin*(林伟)

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For the reactive adsorption process of gasoline desulfurization, the pathway of sulfur removal remained vague. In this work, a comprehensive study shows a clear trail of sulfur during such process, from catalysis to adsorption, by using a combination of advanced in-situ techniques.

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https://doi.org/10.1016/j.gee.2020.05.010


Ion-pair induced solvent extraction of lithium (I) from acidic chloride solutions with tributyl phosphate

Li Cui, Lijuan Wang, Ming Feng, Li Fang, Yanxia Guo, Fangqin Cheng*(程芳琴)

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A new ion-pair induced mechanism for extracting Li+ from acidicchloride solutions by TBP is proposed. The extraction of Li+ is accomplished by forming ion pairs [Li(TBP)n(H2O)m]+[FeCl4] via the coupling effect of the coordination interaction of TBP and Li+, as well as the electrostatic reaction between the Li complex cations and [FeCl4].

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https://doi.org/10.1016/j.gee.2020.05.002

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