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Green Energy & Environment 第六卷第一期已正式出版。
本期共收录文章17篇,其中editorial,research highlight,viewpoint和short review 各1篇,short communication和review article各2篇,research paper9篇。涉及无监督机器学习亮点评述,锂浆料电池发展前景展望,碳负载金催化剂合成氯乙烯,生物质转化乙醇,生物碱降解土壤污染物,二氧化碳催化转化以及金属有机框架的绿色应用等内容。好文多多,敬请阅读~
*封面文章:华东理工大学江浩教授团队研究论文:Confining MoS2 nanocrystals in MOF-derived carbon for high performance lithium and potassium storage。
封底文章:佛山科学技术学院胡飞教授和华南理工大学奚红霞教授团队综述:Recent advancements in metal–organic frameworks for green applications。
图文目录
Editorial
Celebrating the 5th year of Green Energy & Environment (GEE)
Suojiang Zhang*(张锁江)
扫码获取全文
https://doi.org/10.1016/j.gee.2021.02.007
Research highlight Unsupervised machine learning accelerates solid electrolyte discovery Xu Zhang, Bin Tang, Zhen Zhou*(周震) 扫码获取全文 https://doi.org/10.1016/j.gee.2019.12.003 Viewpoint Lithium slurry flow cell, a promising device for the future energy storage Lan Zhang, Xiangkun Wu, Weiwei Qian, Haitao Zhang, Suojiang Zhang*(张锁江) 扫码获取全文 https://doi.org/10.1016/j.gee.2020.09.012 Short communications Stabilizing supported gold catalysts in acetylene hydrochlorination by constructing an acetylene–deficient reaction phase Bolin Wang, Yuxue Yue, Saisai Wang, Shujuan Shao, Zhi Chen, Xianhua Fang, Xiangxue Pang, Zhiyan Pan, Jia Zhao*(赵佳), Xiaonian Li*(李小年) We have proposed a new strategy for constructing a C2H2-deficient reaction phase around the active site by coating an IL film on the surface of Au(H2O)/C, leading to great improvement in the catalytic stability of Au(H2O)/C catalyst. Our work provides a universal method for tuning the stoichiometric balance of reactants. 扫码获取全文 https://doi.org/10.1016/j.gee.2020.06.012 A novel hybrid digestion-gasification process integrated with membranes for efficient conversion of biomass to bio-alcohols Xuezhong He*(何雪忠) An innovative hybrid anaerobic digestion/chemical looping gasification process integrated with membranes was designed for production of bioalcohol used in transport sector from various feedstocks of biomass at a low environmental impact and a low cost. 扫码获取全文 https://doi.org/10.1016/j.gee.2020.04.003 Short review Synthesis of 2,5-diformylfuran from renewable carbohydrates and its applications: A review Jinhang Dai*(代金杭) Catalytic conversion of renewable carbohydrates provides a sustainable access to value-added products. An introduction into recent developments and challenges for the production and application of 2,5-diformylfuran is highlighted herein. 扫码获取全文 https://doi.org/10.1016/j.gee.2020.06.013 Review articles Recent advancements in metal–organic frameworks for green applications Chongxiong Duan, Yi Yu, Jing Xiao, Yuanyuan Li, Pengfei Yang, Fei Hu*(胡飞), Hongxia Xi*(奚红霞) This review summarizes the recent advances of MOFs in the fields of green applications, including carbon capture, harmful gas removal, sewage treatment, and green energy storage. The challenges and prospects of the large-scale commercialized use of MOFs in handling environmental issues are also discussed. 扫码获取全文 https://doi.org/10.1016/j.gee.2020.04.006 The application and progress of bioelectrochemical systems (BESs) in soil remediation: A review Tian Li1, Ruixiang Li1, Qixing Zhou*(周启星) Bioelectrochemical system, as a promising technology, has been widely used in the degradation of different pollutants in different media. This paper focuses on the application of BESs in the degradation of soil pollutants. 扫码获取全文 https://doi.org/10.1016/j.gee.2020.06.026 Research papers Novel HBD-containing Zn (dobdc) (datz) as efficiently heterogeneous catalyst for CO2 chemical conversion under mild conditions Jianwen Lan, Ye Qu, Ping Xu, Jianmin Sun*(孙建敏) Novel 3D MOF Zn (dobdc) (datz) with hydrogen bond donors (HBD) groups showed excellent catalytic performance for CO2 conversion to cyclic carbonates under mild conditions or even room temperature, it presented high catalytic activity within consecutive six runs and was easily recycled by simple centrifugation. 扫码获取全文 https://doi.org/10.1016/j.gee.2019.12.005 Confining MoS2 nanocrystals in MOF-derived carbon for high performance lithium and potassium storage Chen Hu, Kun Ma, Yanjie Hu, Aiping Chen*(陈爱平), Petr Saha, Hao Jiang*(江浩), Chunzhong Li Confined synthesis tactic has been applied to realize the MoS2 nanocrystals well-distributed into the MOF-derived porous carbon for effectively refraining their aggregation and sulfur-dissolution during electrochemical process, exhibiting greatly enhanced lithium and potassium storage performances. 扫码获取全文 https://doi.org/10.1016/j.gee.2020.02.001 Kinetics study of CO2 absorption in potassium carbonate solution promoted by diethylenetriamine Rouzbeh Ramezani*, Renzo Di Felice Reaction kinetics between CO2 and K2CO3 + DETA solution were studied. The density, viscosity, reaction rate constant, reaction order, activation energy and absorption flux of CO2 into solution were reported. 扫码获取全文 https://doi.org/10.1016/j.gee.2019.11.004 Metallurgical pyrolysis toward Co@Nitrogen-doped carbon composite for lithium storage Yanyan Liu, Kang Sun, Jianchun Jiang*(蒋剑春), Wenshu Zhou, Yuan Shang, Chenxia Du, Baojun Li Co based metal−organic frameworks are used as pyrolysis precursor to prepare nitrogen-doped carbon-Co composites possessing core-shell@sheet structure. The experimental results, combining with the theoretical calculation, demonstrate an effective metallurgical method for the construction of elemental state Li storage materials. 扫码获取全文 https://doi.org/10.1016/j.gee.2020.03.003 The adsorption properties of NaY zeolite for separation of ethylene glycol and 1,2-butanediol: Experiment and molecular modelling Pei Xiong, Peng He*(贺鹏), Yixin Qu, Liguo Wang*(王利国), Yan Cao, Shuang Xu, Jiaqiang Chen, Muhammad Ammar, Huiquan Li*(李会泉) NaY zeolite is applied in the adsorption separation of ethylene glycol (EG) and 1,2-butanediol (1,2-BDO). The adsorption properties of NaY was studied by experiment; competition adsorption and diffusion characteristics in different adsorption regions was investigated by molecular modelling. 扫码获取全文 https://doi.org/10.1016/j.gee.2019.12.006 Investigation the improvement of high voltage spinel LiNi0.5Mn1.5O4 cathode material by anneal process for lithium ion batteries Chao Gao, Haiping Liu*(刘海萍), Sifu Bi, Huilin Li, Chengshuai Ma The LiNi0.5Mn1.5O4 sample treated with anneal process presents superior cycling stability compared with the initial sample. The better cycling stability is ascribed to the better electronic conductivity induced by the thin layer originated from anneal process and the more stable crystal structure. 扫码获取全文 https://doi.org/10.1016/j.gee.2020.03.001 Hydrolysis hydrogen production mechanism of Mg10Ni10Ce alloy surface modified by SnO2 nanotubes in different aqueous systems Xiaojiang Hou*(侯小江), Lu Yang, Kaiming Hou, Hongchang Shi, Lei Feng*(冯雷), Guoquan Suo, Xiaohui Ye, Li Zhang, Yanling Yang Simulated seawater (3.5 wt% NaCl) is proved to be an ideal medium for hydrolysis H2 production. And SnO2 nanotubes with unique microstructure, can accelerate the initial hydrolysis rate and enhance the final H2 generation yield of Mg10Ni10Ce. 扫码获取全文 https://doi.org/10.1016/j.gee.2020.05.003 Cross-polymerization between the model furans and phenolics in bio-oil with acid or alkaline catalysts Qing Xu, Xun Hu*(胡勋), Lijun Zhang, Kai Sun, Yuewen Shao, Zhiran Gao, Qing Liu, Chun-Zhu Li*(李春柱) The typical furans (furfural) and phenolics (vanillin) in bio-oil interact with each other, namely cross-polymerization, which leads to changes in the functionalities, structure, morphology, and stability of the insoluble polymer. 扫码获取全文 https://doi.org/10.1016/j.gee.2020.03.009 Understanding the molecular structure of HSW coal at atomic level: A comprehensive characterization from combined experimental and computational study Wei Feng1, Zhuangmei Li1, Hongfeng Gao, Qiang Wang, Hongcun Bai*(白红存), Ping Li*(李平) Hongshiwan (HSW) coal are characterized by materials characterizations. Then molecular model of the coal are built with computer-aided modeling. Thus molecular structure of HSW coal have been depicted and understood at atomic level from experimental and quantum chemical approaches. 扫码获取全文 https://doi.org/10.1016/j.gee.2020.03.013
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