Phys Rep - Water Irregularity.pdf 版权开放

链接：https://doi.org/10.1016/j.physrep.2022.11.001

Abstract

The notion of asymmetrical Hydrogen Bond (O:H−O) Cooperativity and Polarizability (HBCP) has enabled exploration of the core physics behind irregularities of water and ice, particularly, the evolution of mass density, phase stability, energy exchange, and their transition velocity under perturbation. We humbly share the initiatives of the quasisolidity presented between Liquid and Ice, the supersolidity pertained to polarization by electrification or molecular undercoordination, and the H«H and O:Û:O repulsivity owing to the respective injection of excessive protons and lone pairs to the liquid by solvation. ...