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Aqueous charge injection: Salvation bonding dynamics,...

已有 1341 次阅读 2018-7-20 21:10 |个人分类:水之魂|系统分类:论文交流

 

标题: Aqueous charge injection: solvation bonding dynamics, molecular nonbond interactions, and solute extraordinary capabilities 


https://www.tandfonline.com/doi/abs/10.1080/0144235X.2018.1544446

International Reviews in Physical Chemistry 

Volume 37, 2018 - Issue 3-4 Pages 363-558 

74 k words, 478 references, 79 figures, 21 tables 

 

Synopsis:

DPS resolves the fraction and stiffness transition of O:H–O bonds from the mode of ordinary water to their hydration, which reconciles the phonon lifetime, surface stress, solution viscosity, molecular diffusivity, bonding thermodynamics, solution temperature, phase boundary dispersion, critical pressures and temperatures for phase transition, etc. 

 

Keywords: 

aqueous charge injection; molecular nonbond interactions; solvation bonding dynamics; extraordinary solute capabilities; DPS; anti-HB; super-HB; viscosity; surface stress; bond transition; ultrafast IR spectroscopy 

 

Highlight: 

 

 O:H, H-H, O:=:O or ionic or dipolar polarization govern aqueous molecular interactions 

 Bond-nonbond cooperative relaxation and transition dictates the performance of a solution 

 DPS resolves O:H—O bond transition from the mode of ordinary water to hydration shells. 

 Amplifying surface and interface to atomic scale solvation and confinement is fascinating.  




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