研究领域

1.       高效率有机金属配合物磷光发光材料及器件（organic light-emitting devices，OLEDs）；

2.       有机半导体（小分子或高分子）光电材料在太阳能电池（organic photovoltaic cells，OPVs）和场效应晶体管（organic thin-film flied-effect transistors，OTFTs）中应用；

3.       有机/无机纳米材料复合物光电材料及器件；

4.       荧光/磷光探针；

5.       金属有机配合物的合成及性质的研究。

发表论文

1.      X. H. Zhang, J. Shi, G. Y. Shen, F. Gou,J. H. Cheng, X. G. Zhou, and H. F. Xiang,* “Non-conjugated fluorescent molecular cages of salicylaldehyde-basedtri-Schiff bases: AIE, enantiomers, mechanochromism, anion hosts/probes, andcell imaging properties”, Mater. Chem.Front., 2017, 1, 1041-1050.

2.     J. W. Chen, H. F. Xiang,* L.Yang, and X. G. Zhou,* “Synthesis of 2-substituted benzo[b]thiophene via a Pd-catalyzedcoupling of 2-iodothiophenol with phenylacetylene”, RSC Adv., 2017, 7,7753-7757.

3.     F. Gou, J. H. Cheng, X. H. Zhang,G. Y. Shen, X. G. Zhou, and H. F. Xiang,* “Unusual aggregation/gelation-inducedphosphorescence of propeller-type binuclear platinum(II) enantiomers”, Eur. J. Inorg. Chem.,2016,4862-4866.

4.     J. H. Cheng, F. Gou, X. H. Zhang,G. Y. Shen, X. G. Zhou, and H. F. Xiang,* “A class of multiresponsivecolorimetric and fluorescent pH probes via three different reaction mechanismsof Salen complexes: a selective and accurate pH measurement”, Inorg. Chem., 2016, 55, 9221-9229.

5.     F. H Luo, J. Yang, Z. K. Li,* H.F. Xiang, and X. G. Zhou,* “Design and synthesis of2-methyl-7-aminobenzoxazole as auxiliary in the palladium(ii)-catalyzed arylationof a beta-positioned C(sp3)-H bond”, Adv.Synth. Catal., 2016, 358,887-893.

6.     J. Y. Liu, J. H. Cheng, X. F. Ma,X. G. Zhou, and H. F. Xiang,* “Photophysical properties and pH sensingapplications of luminescent salicylaldehyde derivatives”, Res. Chem. Intermed., 2016, 42, 5027-5048.

7.     X. F. Ma, R. Sun, J. H. Cheng, J.Y. Liu, F. Gou, H. F. Xiang,* and X. G. Zhou,* “Fluorescenceaggregation-caused quenching versus aggregation-induced emission: a visualteaching technology for undergraduate chemistry students”, J. Chem. Educ., 2016, 93, 345-350.

8.     J. H.Cheng, Y. X. Li,R. Sun, J. Y. Liu,F. Gou, X. G. Zhou,H. F. Xiang,* and J. Liu*, “FunctionalizedSalen ligands linking with non-conjugated bridges: unique and colorfulaggregation-induced emission, mechanism, and applications” J. Mater. Chem. C,2015,3, 11099-11110.

9.      J. H. Cheng, X. G. Zhou, and H. F. Xiang,* “Fluorescentmetalion chemosensors via cation exchange reactions of complexes, quantumdots, andmetal-organic frameworks”, Analyst, 2015,140, 7082-7115.

10.  L. P. Zhang, J. N. Pu, J. Y. Ren, Z. K. Li, H. F.Xiang, and X. G. Zhou,* “Synthesis of α-ketoamides by copper-catalyzedreactions of phenylacetic acids with N,N-dialkylformamides”, Synth. Commun., 2015, 45, 1848-1856.

11.  F. H. Luo, J. Yang, Z. K. Li, H. F. Xiang,and X. G. Zhou,* “Palladium-catalyzed C–H bond acylation of acetanilides withbenzylic alcohols under aqueous conditions”, Eur. J. Org. Chem., 2015, 2463-2469.

12.  R. R Long, X. F. Yan, Z. Q. Wu, Z. K. Li, H. F.Xiang and X. G. Zhou,* “Palladium-catalyzed direct arylation of phenolswith aryl iodides”, Org. Biomol. Chem.,2015, 13, 3571-3574.

13.  X. F. Ma, J. H. Cheng, J. Y. Liu, X. G. Zhou, and H.F. Xiang,* “Ratiometric fluorescent pH probes based on aggregation-inducedemission-active salicylaldehyde azines”, NewJ. Chem., 2015, 39, 492-500.

14.  R. Che, Z. Q. Wu, Z. K. Li, H. F. Xiang, andZ. X. Zhou,* “Synthesis of dibenzothiophenes by Pd-catalyzed dual C-Hactivation from diaryl sulphides”, Chem.Eur. J., 2014, 20, 7258-7261.

15.  L. Pan, L. T. Yu, Z. Q. Wu, Z. K. Li, H. F. Xiang,and X. G. Zhou,* “Quaternary ammonium salt as alkylation agent inthree-component reactions for the synthesis of benzothiazoles in water”, RSC Adv., 2014, 4, 27775-27779.

16.  J.H. Cheng, X. F. Ma, Y. H. Zhang, J. Y. Liu, X. G. Zhou, and H. F. Xiang,*“Optical chemosensors based on transmetalation of Salen-based Schiff basecomplexes”, Inorg. Chem., 2014,53, 3210-3219.

17.  J.H. Cheng, Y. H. Zhang, X. F. Ma, X. G. Zhou, and H. F. Xiang,* “Colorimetricand fluorescent pH and Cu²⁺ probes induced by photoisomerization ofa maleonitrile-based Salen ligand”, Chem. Commun., 2013, 49, 11791-11793.

18.  Y. Y. Qu, Z. K. Li,* H. F. Xiang, and X. G.Zhou,* “Copper(II)-catalyzed reactions of dimethylformamide with phenylacetonitrileand sulfur to form N,N-dimethylthioamides”, Adv. Synth. Catal., 2013, 355, 3141 – 3146.

19.  H.L. Xu, H. Deng,* Z. K. Li, H. F. Xiang, and X. G. Zhou,* “Synthesis of thioamides by catalyst-free three-componentreactions in water”, Eur. J. Org. Chem.,2013, 7054-7057.

20.  F.Ke, X. L. Chen, Z. K. Li, H. F. Xiang and X. G. Zhou,*“Microwave-assisted copper-catalyzed hydroxylation of aryl halides in water”, RSCAdv., 2013, 3,22837-22840.

21.  J.H. Cheng, K. Y. Wei, X. F. Ma, X. G. Zhou, and H. F. Xiang,* “Synthesisand photophysical properties of colorful Salen-type Schiff bases”, J. Phys.Chem. C, 2013, 117,16552-16563.

22.  Z.Q. Wu, S. Chen, C. X. Hu, Z. K. Li, H. F. Xiang, and Xiangge Zhou,*“Palladium-catalyzed C-Hortho arylation of benzoic acids with diaryliodonium salts in water”, ChemCatChem,2013, 5,2839 – 2842.

23.  Z.Q. Wu, F. H. Luo, S. Chen, Z. K. Li, H. F. Xiang, and Xiangge Zhou,*“Palladium-catalyzed para-selective arylation of phenols with aryl iodides inwater”, Chem. Commun., 2013,49, 7653-7655.

24.  H.F. Xiang,* J. H. Cheng, X. F. Ma, X. G. Zhou, and J. J.Chruma, “Near-infrared phosphorescence: materials and applications”, Chem.Soc. Rev., 2013,42, 6128-6185.

25.  Z.K. Li, F. Ke,* H. Deng, H. L. Xu, H. F. Xiang, and X. G. Zhou,*“Synthesis of disulfides and diselenides by copper-catalyzed coupling reactionsin water”, Org. Biomol. Chem., 2013,11, 2943-2946.

26.  L.Zhou, Y. Feng, J. H. Cheng, N. Sun, X. G. Zhou, and H. F. Xiang,*“Simple, selective, and sensitive colorimetric and ratiometricfluorescence/phosphorescence probes for platinum(II) based on Salen-type Schiffbases”, RSC Adv., 2012, 2, 10529-10536.

27.  Y. Feng, J. H. Cheng, L. Zhou, X. G.Zhou, and H. F. Xiang,* “Ratiometric optical oxygen sensing: a review in respect ofmaterial design”, Analyst, 2012, 137, 4885-4901.

28.  L. T. Yang, D. Wu,* H.F. Xiang, X. G. Zhou, and Y. F. Deng,* “Synthesis and structure and opticalproperties of a zinc(II) tetrakis(phenylbutadiynyl)porphyrin”, Heterocycles,2012, 85, 1987-1996.

29. L. Zhou, P. Y. Cai, Y. Feng, J. H. Cheng, H. F. Xiang,*J. Liu,* D. Wu,* and X. G. Zhou, “Synthesis and photophysical properties ofwater-soluble sulfonato-Salen-type Schiff bases and their applications offluorescence sensors for Cu²⁺ in water and living cells”, Anal.Chim. Acta, 2012, 735, 96-106.

30. H. F. Xiang,* L. Zhou, Y. Feng, J. H. Cheng, D. Wu, and X. G.Zhou,* “Tunable fluorescent/phosphorescent platinum(II) porphyrin-fluorenecopolymers for ratiometric dual emissive oxygen sensing”, Inorg. Chem., 2012,51, 5208-5212.

31. L. Zhou, Z.X. Xu, Y. Zhou, Y. Feng, X. G. Zhou, H. F. Xiang,* and V. A. L. Roy,* “Structure-chargetransport relationship of 5,15-dialkylated porphyrins”, Chem. Commun., 2012, 48, 5139-5141.

32. L. T. Yu, X.G. Zhou,* D. Wu, and H. F. Xiang, “Synthesisof phenazines by Cu-catalyzed homocoupling of 2-halogen anilines in water”, J.Organomet. Chem., 2012, 705, 75-78.

33. L. L. Li, H. F. Xiang, X. G.Zhou,* M. L. Li, and D. Wu,* “Detection of Fe³⁺ and Al³⁺by test paper”, J. Chem. Educ., 2012, 89, 559-560.

34. L. L. Li, P.Y. Cai, Y. F Deng, L. T. Yang, X. He, L. S. Pu, D. Wu,* J. Liu,* H. F. Xiang,and X. G. Zhou,* “Water-soluble porphyrin-based logic gates”, J. Porphyr.Phthalocya.,2012, 16,72-76.

35. K. H. Low, Z. X. Xu, H. F. Xiang, S. S. Y. Chui, V. A. L. Roy,and C. M. Che,*“Bis(5,7-dimethyl-8-hydroxyquinolinato)platinum(II) complex for efficient organicheterojunctionsolar cells”, Chem. Asian J., 2011, 6, 3223 -3229.

36. Y. Y. Qu, F. Ke, L. Zhou, Z. K. Li, H. F. Xiang, D. Wu, and X. G.Zhou,* “Synthesis of 3-indole derivatives by copper sulfonato Salen catalyzedthree-component reactions in water”, Chem. Commun., 2011, 47, 3912 – 3914.

37.  F. Ke, Z. K. Li, H. F.Xiang, and X. G. Zhou,* “Catalytic hydroalkoxylation of alkenes byiron(III) catalyst”, Tetrahedron Lett., 2011, 52, 318 –320.

38.  L. H. Jing, J. T. Wei, L.Zhou, Z. Y. Huang, Z. K. Li, D. Wu, H. F. Xiang, and X. G. Zhou,* “Highly enantioselectivemichael addition of malononitrile to vinylogous imine intermediates generatedin situ from arylsulfonyl indoles”, Chem. Eur. J., 2010, 16, 10955 – 10958.

39.  Z. Q. Wu , Z. Q. Jiang,D. Wu, H. F. Xiang, and X. G. Zhou,* “A simple and efficient catalytic system for coupling aryl halides withaqueous ammonia in water”, Eur. J. Org. Chem., 2010, 1854 – 1857.

40.  Z. X. Xu, H. F. Xiang,V. A. L. Roy, S. S. Y. Chui, Y.Wang, P. T.Lai, and C. M. Che,* “Organic field-effecttransistors fabricated with N,N’-substituted dialkyl-1,3,8,10-tetramethylquinacridone compounds”,Appl. Phys. Lett., 2009,95, 123305.

41.  Z. X. Xu, H. F. Xiang,V. A. L. Roy, S. S. Y. Chui, C. M. Che,* and P. T. Lai,“Field-effecttransistor fabricated with nickel (II) etioporphyrin-I micrometer-sizedcrystals”,Appl. Phys.Lett., 2008,93,223305.

42.  C. M. Che,* H. F. Xiang, S. S. Y. Chui, Z. X. Xu, V. A. L. Roy, J. J. Yan, W. F. Fu, P. T. Lai, andI. D. Williams, “A high-performance organic field-effecttransistor based on platinum(II) porphyrin: peripheral substituents onporphyrin ligand significantly affect film structure and charge mobility”, Chem.Asian J., 2008, 3, 1092 - 1103.

43.  P. Stalling,*V. A. L. Roy,* Z.X. Xu, H.F. Xiang,and C.M. Che, “Metal-insulator-metaltransistors”, Adv. Mater.,2008, 20,2120 -2124.

44.  H. F. Xiang, Z. X. Xu, V. A. L. Roy, S. C. Chan, C. M. Che,* and P. T. Lai, “Deep-redto near-infrared electrophosphorescence based on bis-(8-hydroxyquinolato)platinum(II) complexes”, Appl. Phys. Lett., 2008,92, 163305.

45.  H. F. Xiang, Z. X. Xu, V. A. L. Roy,C. M. Che,* P. T. Lai, P. J. Zeng,* F. F. Niu, Y. W. Liu, W. Q. Tang, C. J. He,and H. B. Niu, “Star-configuredcarbazole as an efficient near-ultraviolet emitter and hole-transportingmaterial for organic light-emitting devices”, Appl. Phys. Lett., 2008,92, 073305.

46.  H. F. Xiang, S. W. Lai, P. T. Lai, and C. M. Che, “Highly efficient OLEDs with phosphorescent materials” (Chapter7, Phosphorescent platinum(II) materials for OLED applications), editedby H. Yersin, Wiley-VCH Verlag GmbH, 2007, 259 - 282.

47.  V. A. L. Roy,* Z. X. Xu, P.Stalling, H. F. Xiang,B. P. Yan, and C. M. Che, “Nanocomposite field effect transistors basedon zinc oxide/polymer blends”,Microprocesses and Nanotechnology, 2007, 104 - 105.

48.  W. B.Chen, H. F. Xiang, X. Z. Xiang, V. A. L. Roy, B. P. Yan, C. M. Che*, and P. T. Lai, “Improving efficiency of organic photovoltaic cells with pentacene-doped CuPc layer”, Appl. Phys. Lett., 2007, 91,191109.

49.  B. P. Yan, C. C. C. Cheung, S. C. F. Kui, H. F.Xiang, V. A. L. Roy,S. J. Xu, and C. M.Che,* “Efficient white organic light-emitting devices (WOLEDs) based onphosphorescent platinum (II)/fluorescent dual emitting layers”, Adv. Mater., 2007, 19,3955- 3603.

50.  Z. X. Xu, V. A. L. Roy, P.Stalling, M. Muccini, S. Toffanin,H. F. Xiang, and C. M. Che,* “Nanocomposite field effect transistors based on zinc oxide/polymerblends”, Appl. Phys.Lett., 2007, 90, 223509.

51.  H. F. Xiang, X. Z. Xiang, V. A. L. Roy, C. M. Che, and P. T. Lai,* “Method for measurement of thedensity of thin films of small organic molecules”, Revi. Sci. Inst., 2007, 78,034104.

52.  H.F. Xiang, S. C. Chan, K. K. Y. Wu, C. M. Che*, and P. T.Lai, “High-efficiencyred electrophosphorescence based on neutral bis(pyrrole)-diimine platinum(II) complex”, Chem. Commun., 2005, 1408 - 1410.

53.  H. F. Xiang, S. C. Chan, C. M. Che,* P. T. Lai, and P. C. Chui, “High-efficiencyelectrophosphorescent organic light-emitting devices based on Schiff baseplatinum(II) complexes”, Organic Light-Emitting Materials and Devices VIII (SPIE),2004, 5519, 296 - 303.

54. H. F. Xiang, C. N. Li, S. C. Yu, C. M. Che,* P. T. Lai, and P. C. Chui, “Organic, polymer andorganic/inorganic hybrid light-emitting devices based on phosphorescentfluorinated platinum(II) porphyrin”, Organic Light-Emitting Materials andDevices VIII (SPIE), 2004,5519, 218 - 225.

55. C. M. Che,*S. C. Chan,H. F. Xiang,M. C. W. Chan,Y. Liu,and Y. Wang,“Tetradentate Schiff base platinum(II) complexes as new class of phosphorescentmaterials for high-efficiency and white-light electroluminescent devices”, Chem.Commun., 2004, 1484 - 1485.

56.  H. F. Xiang, S. C. Yu, C. M. Che*, and P. T. Lai, “Efficient white and red light emission from GaN/tris-8-hydroxyquinolatoaluminum/platinum(II) meso-tetrakis(pentafluorophenyl) porphyrin hybridlight-emitting diodes”, Appl. Phys. Lett., 2003, 83, 1518 - 1520.

57. W. Lu, H.F. Xiang, N. Y. Zhu, and C. M. Che,* “The ³(pi-pi*) emission of Cy₃PAu(CoC)_nAuPCy₃(n=3, 4). Effect of chain length upon acetylenic ³(pi-pi*) emission”, Organometallics, 2002, 21, 2343 - 2346.

58. Z. B. Wang* and H. F. Xiang, “A spectrophotometric determination oftungsten in electroplating solution and electroplated layer”, Fujiananalysis & testing (Chinese), 1997, 6, 689-693.