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【催化书籍推荐】界面催化——Interfacial Catalysis

已有 4953 次阅读 2007-10-16 12:13 |个人分类:催化资源收藏


界面催化——Interfacial Catalysis


ISBN: 0824708393
Title: Interfacial Catalysis
Author: Alexander G. Volkov
Publisher: CRC
Publication Date: 2002-12-12
Number Of Pages: 680


Editorial Description
A comprehensive volume on interfacial catalysis, this book includes contributions from an international group of specialists in chemistry, environmental science, informatics, physiology, nuclear energy, and physics. The editor has organized the material into the main topics of fundamental characteristics, phase transfer catalysis, reversed micelles, biological aspects, and interfacial photocatalysis. Individual topics include self-organized microheterogeneous structures, nanochemistry, interfaci  ...read whole description

Preface
Interfacial catalysis plays a key role in many chemical, physical, and biological processes. The past decade has witnessed a huge increase of research interest in the study of interfacial catalysis at liquid interfaces. Processes taking place at the interface between two immiscible liquid phases are fundamental to life since virtually all energy conversion processes in living organisms occur at liquid interfaces. The properties of liquid–liquid interfaces are very important for a variety of industries, including biotechnology, organic synthesis, nanochemistry, catalysis, pharmaceuticals, cosmetics, paints, detergents, oil extraction processes, and mining. The interface between two immiscible liquids with immobilized photosynthetic pigments serves as a convenient model for investigating photoprocesses that are accompanied by spatial separation of charges. The efficiency of charge separation is defined by the quantum yield of any photochemical reaction. Heterogeneous systems in which the oxidants and the reductants are either in different phases or sterically separated are the most effective in this regard. Different solubilities of the substrates and reaction products in the two phases of heterogeneous systems can alter the redox potential of reactants, making it possible to carry out reactions that cannot be performed in a homogeneous phase. The book is organized into five parts.

Part I consists of seven chapters and deals with fundamental aspects of interfacial phenomena such as catalytic properties of liquid interfaces, electrochemistry at polarized interfaces, ion solvation and resolvation, interfacial potentials, separations, and interfacial catalysis in metal complexation and in enhanced oil recovery.

Part II contains four chapters about history, theory, molecular mechanisms, synthesis, and experimental systems in phase transfer catalysis.

Part III deals with micellar catalysis, enzymology, and photochemical reactions in reversed micelles.

The chapters in Part IV discuss biological aspects of interfacial and membrane catalysis including bioelectrocatalysis, ion channels, mechanisms of respiration and photosynthesis, membrane catalysis, and ion transport processes.

Part V, which is about interfacial photocatalysis, includes such topics as nanochemistry, nanoparticles, self-organized microheterogeneous structures, photosensitizers, and photocatalytic oxygen evolution. The experimental systems and theoretical analysis of interfacial photocatalytic systems are also discussed in Chapters 14, 15, and 18. I would like to extend my thanks to the authors for the time they spent on this project and for teaching us about their work on nanochemistry and interfacial catalysis. I also thank our Acquisitions Editor, Anita Lekhwani, and our Production Editor, Joseph
Stubenrauch, for their friendly and courteous assistance.
Alexander G. Volkov
Copyright © 2003 by Taylor & Francis Group, LLC

Contents
Preface
Contributors
Part I. Interfacial Phenomena
1. Interfacial Catalysis at Oil/Water Interfaces
Alexander G. Volkov
2. Electrochemistry of Chemical Reactions at Polarized Liquid–Liquid Interfaces
Takashi Kakiuchi
3. Interfacial Catalysis in Metal Complexation
Hitoshi Watarai
4. The Role of Water Molecules in Ion Transfer at the Oil/Water Interface
Toshiyuki Osakai
5. Interfacial Potential and Distribution Equilibria Between Two Immiscible Electrolyte Solutions
Le Quoc Hung
6. Use of Cyclodextrins or Porous Inorganic Supports to Improve Organic/ Aqueous Interfacial Transfers
Martine Urrutigo?¨ty and Philippe Kalck
7. Ultrathin Films: Their Use in Enhanced Oil Recovery and in Interfacial Catalysis
Lu Zhang, Sui Zhao, Jia-Yong Yu, Angelica L. Ottova´, and H. Ti Tien
Part II. Phase Transfer Catalysis
8. Phase Transfer Catalysis
Mieczysiaw Ma?kosza and Michai Fedoryn´ski
9. Liquid–Liquid Phase Transfer Catalysis: Basic Principles and Synthetic Applications
Domenico Albanese
10. Phase Transfer Catalysis: Fundamentals and Selected Systems
Jing-Jer Jwo
11. Interfacial Mechanism and Kinetics of Phase-Transfer Catalysis
Hung-Ming Yang and Ho-Shing Wu
Part III. Micellar Catalysis
12. Enzymes in Reverse Micelles (Microemulsions): Theory and Practice
Andrey V. Levashov and Natalia L. Klyachko
13. Micellar Catalysis
Vincent C. Reinsborough
14. Multiple Effects of Water Pools and Their Interfaces Formed by Reversed Micelles on Enzymic Reactions and Photochemistry
Ayako Goto, Yuko Ibuki, and Rensuke Goto
Part IV. Interfacial Biocatalysis and Membrane Catalysis
15. Supported Planar BLMs (Lipid Bilayers): Formation, Methods of Study, and Applications
Angelica L. Ottova´ and H. Ti Tien
16. Bioelectrocatalysis
Kenji Kano and Tokuji Ikeda
17. Energetics and Gating of Narrow Ionic Channels: The Influence of Channel Architecture and Lipid–Channel Interactions
Peter C. Jordan, Gennady V. Miloshevsky, and Michael B. Partenskii
18. Biocatalysis: Electrochemical Mechanisms of Respiration and Photosynthesis
Alexander G. Volkov
19. New Types of Membrane Reactions Mimicking Biological Processes
Sorin Kihara
20. Ion-Transport Processes Through Membranes of Various Types: Liquid Membrane, Thin Supported Liquid Membrane, and Bilayer Lipid Membrane
Osamu Shirai and Sorin Kihara
Part V. Interfacial Photocatalysis
21. Development of Structurally Organized Photocatalytic Systems for Photocatalytic Hydrogen Evolution on the Basis of Lipid Vesicles with Semiconductor Nanoparticles Fixed on Lipid Membranes
Oxana V. Vassiltsova and Valentin N. Parmon
22. Catalysis and Photocatalysis at Polarized Molecular Interfaces: An Electrochemical Approach to Catalytic Processes Based on Two-Phase
Systems, Self-Organized Microheterogeneous Structures, and Unsupported Nanoparticles
Riikka Lahtinen, Henrik Jensen, and David J. Ferm?´n
23. Photosensitizers at Interfaces of Model Membranes
Sarah A. Gerhardt and Jin Z. Zhang


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