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CVOCs在Mn-Ti催化剂上的催化燃烧进展:L酸性位的作用(ACB,詹望成、郭杨龙教授)

已有 672 次阅读 2020-10-4 15:04 |个人分类:科研点滴启发|系统分类:科研笔记

https://www.sciencedirect.com/science/article/abs/pii/S0926337320309929


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Highlights


  • •MnxTi1-xOy shows different acidity and reducibility by adjusting Mn/Ti ratio.

  • •Mn-O-Ti solid solution accounts for more Lewis acidic sites on catalyst surface.

  • •Surface acidity determines catalytic activity for VC oxidation when Mn/Ti > 0.4.

  • •Mn0.4Ti0.6Ox with more acid sites and certain reducibility has a high activity.

  • •The mechanism of Lewis acid participating in the VC oxidation is proposed.

Abstract

A series of Mn-Ti composite oxides (MnyTi1−yOx) were prepared via the sol-gel method, and their reducibility and surface acidity were controlled by adjusting the Mn/Ti molar ratio. In addition, as a model reaction, the catalytic activity of Mn-Ti composite oxides for the deep oxidation of vinyl chloride (VC) was evaluated. It was found that the catalyst surface acidity played a decisive role in the oxidation of VC, on the condition that the catalyst reducibility was superior to that of Mn0.4Ti0.6Ox. Consequently, a linear relationship between the surface acidity of the MnyTi1−yOx catalysts (y≥0.4) and the reaction rate of the VC oxidation process was observed. Moreover, the influence of Lewis acidic sites originating from Ti species on the catalytic activity of the MnyTi1−yOx catalysts was revealed. These results could lead to an efficient strategy for enhancing the CVOC oxidation reaction through finely tuning reducibility and surface acidity of the catalyst.




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